基于化学修饰氧化石墨烯自组装沉积法制备的彩色碳纤维性能研究

doi:10.19936/j.cnki.2096-8000.20220328.006

复合材料科学与工程 ›› 2022, Vol. 0 ›› Issue (3): 45-50.DOI: 10.19936/j.cnki.2096-8000.20220328.006

基于化学修饰氧化石墨烯自组装沉积法制备的彩色碳纤维性能研究

侯静¹, 杨晨¹, 刘亲亲², 雷艳妮², 许培俊^1,2*

1.长安大学材料科学与工程学院,西安710064;
2.陕西航天技术应用研究院有限公司,西安710199

收稿日期:2021-07-26 出版日期:2022-03-28 发布日期:2022-04-24
通讯作者: 许培俊(1984-),男,博士,教授,博士生导师,主要从事聚合物基复合材料方面的研究,xupeijun@chd.edu.cn。
作者简介:侯静(1997-),女,硕士研究生,主要从事功能碳纤维复合材料界面性能方面的研究。
基金资助:
国家自然科学基金面上项目(51978072);中央高校基本科研业务费资助项目(300102319207);中国博士后基金(2018M643552)

Properties of color carbon fiber prepared by self-assembly deposition of chemically modified graphene oxide

HOU Jing¹, YANG Chen¹, LIU Qin-qin², LEI Yan-ni², XU Pei-jun^1,2*

1. School of Materials Science and Engineering, Chang'an University, Xi'an 710064, China;
2. Shaanxi Aerospace Technology Application Research Institute Co., Ltd., Xi'an 710199, China

Received:2021-07-26 Online:2022-03-28 Published:2022-04-24

摘要/Abstract

摘要： 碳纤维因其高比强度、比模量等优异性能而广泛应用于航空、汽车、能源等领域,如何在保持碳纤维复合材料优异力学性能的同时兼顾其功能性和智能性逐渐成为复合材料未来的发展方向。氧化石墨烯(GO)水溶液在碳纤维上通过沉积自组装能够形成类似一维光子晶体的结构色涂层,但该GO涂层与碳纤维间仅存在物理吸附力,界面性能不足。本文利用硅烷偶联剂(APTES)对GO进行化学修饰,将修饰后的GO(mGO)同样通过自组装的方法在碳纤维表面沉积制备出彩色碳纤维。探究APTES含量对mGO-CF界面剪切强度、拉伸力学性能的影响及生色机理。结果表明,APTES中氨基官能团的引入能够显著改善碳纤维与mGO的界面黏结性能,且多层膜结构的mGO可以弥补碳纤维表面缺陷,提高单丝碳纤维强度。与GO-CF相比,mGO-CF-15的单丝拉伸强度提高了12.4%,界面剪切强度提高了13.5%。

关键词: 碳纤维, 氧化石墨烯, 界面剪切强度, 单丝拉伸强度, 复合材料

Abstract: Carbon fiber has been widely used in aviation, aerospace, automotive, energy and other fields due to its high specific strength, high specific modulus and other excellent properties. How to maintain the excellent mechanical properties of carbon fiber composites while taking into consideration its functionality and intelligence has gradually become the future development direction of composites. Graphene oxide (GO) aqueous solution can form a structural color coating similar to one-dimensional photonic crystal through deposition and self-assembly on carbon fiber. However, there is only physical absorbing force between GO coating and carbon fiber, and the interface performance is insufficient. In this paper, GO is chemically modified with silane coupling agent (APTES). The modified GO (mGO) is also deposited on the surface of carbon fibers by self-assembly method to prepare color carbon fibers. The influence of APTES content on interfacial shear strength, tensile mechanical properties and coloring mechanism are investigated. The results show that the introduction of amino functional group in APTES can significantly improve the interfacial bonding property between carbon fiber and GO. mGO with multilayer structure can remedy the surface defects of carbon fiber and improve the strength of monofilament fiber. Compared with GO-CF, the monofilament tensile strength and interfacial shear strength of mGO-CF-15 are increased by 12.4% and 13.5% respectively.

Key words: carbon fiber, graphene oxide, interfacial shear strength, monofilament tensile strength, composites

中图分类号:

TB332

侯静, 杨晨, 刘亲亲, 雷艳妮, 许培俊. 基于化学修饰氧化石墨烯自组装沉积法制备的彩色碳纤维性能研究[J]. 复合材料科学与工程, 2022, 0(3): 45-50.

HOU Jing, YANG Chen, LIU Qin-qin, LEI Yan-ni, XU Pei-jun. Properties of color carbon fiber prepared by self-assembly deposition of chemically modified graphene oxide[J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(3): 45-50.

参考文献

[1] GIEBEL E, HERRMANN T, SIMON F, et al. Surface modification of carbon fibers by free radical graft-polymerization of 2-hydroxyethyl methacrylate for high mechanical strength fiber-matrix composites[J]. Macromolecular Materials & Engineering, 2017, 302(12): 1-5.
[2] FRANK E, HERMANUTZ F, BUCHMEISER M R. Carbon fibers: Precursors, manufacturing, and properties[J]. Macromolecular Materials and Engineering, 2012, 297(6): 493-501.
[3] LIU Y, KUMAR S. Recent progress in fabrication, structure, and properties of carbon fibers[J]. Polymer Reviews, 2012, 52(3): 234-258.
[4] CHEN X, WANG X, LI L, et al. Preparation and microwave absorbing properties of nickel-coated carbon fiber with polyaniline via in situ polymerization[J]. Journal of Materials Science Materials in Electronics, 2016, 27(6): 5607-5612.
[5] ABDELAL N. Electromagnetic interference shielding of stitched carbon fiber composites[J]. Journal of Industrial Textiles, 2020, 49(6): 773-790.
[6] DENG C, JIANG J, LIU F, et al. Influence of graphene oxide coatings on carbon fiber by ultrasonically assisted electrophoretic deposition on its composite interfacial property[J]. Surface and Coatings Technology, 2015, 272(4): 176-181.
[7] LIN S, FLEMING J, HETHRINGTON D, et al. A three-dimensional photonic crystal operating at infrared wavelengths[J]. Nature, 1998, 394(6690): 251-253.
[8] 史文静, 张佩华. 热转移压印纳米结构在化学纤维结构显色上的应用和研究[J]. 国际纺织导报, 2008, 36(3): 28-33, 40.
[9] KOLLE M, LETHBRIDGE A, KREYSING M, et al. Bio-inspired band-gap tunable elastic optical multilayer fibers[J]. Advanced Materials, 2013, 25(15): 2239-2245.
[10] LI P, WONG M, ZHANG X, et al. Tunable lyotropic photonic liquid crystal based on graphene oxide[J]. ACS Photonics, 2014, 1(1): 79-86.
[11] PARKER A R, MARTINI N. Structural colour in animals: Simple to complex optics[J]. Optics & Laser Technology, 2006, 38(4-6): 315-322.
[12] TONG L, QI W, WANG M, et al. Tunable design of structural colors produced by pseudo-1D photonic crystals of graphene oxide[J]. Small, 2016, 12(25): 3433-3443.
[13] JALILI R, ABOUTALEBI S H, ESRAFILZADEH D, et al. Organic solvent-based graphene oxide liquid crystals: A facile route toward the next generation of self-assembled layer-by-layer multifunctional 3D architectures[J]. ACS Nano, 2013, 7(5): 3981-3990.
[14] HE L, YE J, SHUAI M, et al. Graphene oxide liquid crystals for reflective displays without polarizing optics[J]. Nanoscale, 2015, 7(5): 1616-1622.
[15] LUO Z, VORA P M, MELE E J, et al. Photoluminescence and band gap modulation in graphene oxide[J]. Applied Physics Letters, 2009, 94(11): 1-3.
[16] SHANG J, LIN M, LI J, et al. The origin of fluorescence from graphene oxide[J]. Scientific Reports, 2012, 2(1): 1-8.
[17] HUANG S Y, WU G P, CHEN C M, et al. Electrophoretic deposition and thermal annealing of a graphene oxide thin film on carbon fiber surfaces[J]. Carbon, 2013, 52(2): 613-616.
[18] ZHANG X, FAN X, YAN C, et al. Interfacial microstructure and properties of carbon fiber composites modified with graphene oxide[J]. ACS Applied Materials & Interfaces, 2012, 4(3): 1543-1552.
[19] WANG C, LI J, YU J, et al. Grafting of size-controlled graphene oxide sheets onto carbon fiber for reinforcement of carbon fiber/epoxy composite interfacial strength[J]. Composites Part A: Applied Science and Manufacturing, 2017, 101(5): 511-520.
[20] 刘秀影, 宋英, 李存梅, 等. 氧化石墨烯接枝碳纤维新型增强体的制备与表征[J]. 无机化学学报, 2011, 27(11): 2128-2132.
[21] 廖俊, 陈圣云, 康宇峰, 等. 硅烷偶联剂及其在复合材料中的应用[J]. 化工新型材料, 2001, 29(9): 26-28.
[22] 王慧茹, 王鑫, 赵雄燕. 硅烷偶联剂改性氧化石墨烯的制备及表征[J]. 应用化工, 2019, 48(1): 105-107.
[23] WU Q, YANG X, WAN Q, et al. Layer-by-layer assembled nacre-like polyether amine/GO hierarchical structure on carbon fiber surface toward composites with excellent interfacial strength and toughness[J]. Composites Science and Technology, 2020, 198(5): 1-24.
[24] 雷振坤, 亢一澜, 王怀文, 等. 单纤维细丝微力学性能实验研究[J]. 实验力学, 2005, 20(1): 72-76.
[25] MRAD M, MONTRMOR M F, DHOUIBI L, et al. Deposition of hybrid 3-GPTMS's film on AA2024-T3: Dependence of film morphology and protectiveness performance on coating conditions[J]. Progress in Organic Coatings, 2012, 73(2-3): 264-271.
[26] PARHIZKER N, SHAHRABI T, RAMEZANZADEH B. A new approach for enhancement of the corrosion protection properties and interfacial adhesion bonds between the epoxy coating and steel substrate through surface treatment by covalently modified amino functionalized graphene oxide film[J]. Corrosion Science, 2017, 123(7): 55-75.
[27] 张双红, 杨波, 孔纲, 等. 氧化石墨烯/硅烷转化膜层的研究进展[J]. 电镀与涂饰, 2020, 39 (11): 733-739.
[28] 南京玻璃纤维研究设计院有限公司. 碳纤维单丝拉伸性能的测定: GB/T 31290—2014[S]. 北京: 中国国家标准化管理委员会, 2014.
[29] WANG C, LI J, SUN S, et al. Electrophoretic deposition of graphene oxide on continuous carbon fibers for reinforcement of both tensile and interfacial strength[J]. Composites Science and Technology, 2016, 135(5): 46-53.
[30] 杜善义, 王晓宏, 张博明, 等. 单丝复合体系界面力学行为的表征[J]. 哈尔滨工业大学学报, 2010, 42(7): 1095-1099.

基于化学修饰氧化石墨烯自组装沉积法制备的彩色碳纤维性能研究

Properties of color carbon fiber prepared by self-assembly deposition of chemically modified graphene oxide

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王孟, 刘程, 张玉, 贾航, 乔越, 蹇锡高. 成型温度对CF/PPEK复合材料的缺陷和力学性能影响[J]. 复合材料科学与工程, 2024, 0(3): 5-12.
[2]	史洪源, 任文坚, 党杰, 周鹏. 玻璃纤维增强复合材料超声检测声场的CIVA仿真与试验研究[J]. 复合材料科学与工程, 2024, 0(3): 20-24.
[3]	杨思鑫, 曹忠亮, 顾付伟. 双三角点阵夹芯结构低速冲击下的动态响应与失效机制[J]. 复合材料科学与工程, 2024, 0(3): 25-34.
[4]	张斌, 赵晶, 王世杰. Kagome点阵结构参数对其压缩特性的影响及轻质化设计[J]. 复合材料科学与工程, 2024, 0(3): 35-42.
[5]	王宇轩, 曹东风, 胡海晓, 李书欣. 计及层内和层间的L形层合板失效的数值研究[J]. 复合材料科学与工程, 2024, 0(3): 43-53.
[6]	耿健, 董九志, 梅宝龙, 蒋秀明. 三维四向碳/碳复合材料力学性能预测与试验验证[J]. 复合材料科学与工程, 2024, 0(3): 54-60.
[7]	高坤, 张兆恒, 邢亚娟, 左小彪, 王博尧, 赵泽华. 含磷POSS阻燃乙烯基酯树脂性能研究[J]. 复合材料科学与工程, 2024, 0(3): 61-64.
[8]	郑子君, 乔英, 邵家儒. 基于机器视觉的短纤维复合材料的取向度提取方法[J]. 复合材料科学与工程, 2024, 0(3): 65-72.
[9]	许晓婷, 郝恩全, 邵慧奇, 邵光伟, 毕思伊, 陈南梁, 蒋金华. 三维大隔距机织间隔织物柔性复合材料的服役性能研究[J]. 复合材料科学与工程, 2024, 0(3): 73-78.
[10]	苏桐, 胡果馨, 刘振. 全碳纤维复合材料太阳能无人机机翼结构优化设计[J]. 复合材料科学与工程, 2024, 0(3): 79-83.
[11]	伍强, 赵凯, 刘鹏飞, 张涛涛, 朱德勇. Z形纤维增强复合材料层压板固化变形分析[J]. 复合材料科学与工程, 2024, 0(3): 84-90.
[12]	宋贵宾, 黄光启, 杨胜春. 复合材料层压板胶接挖补修理分析方法及影响因素研究[J]. 复合材料科学与工程, 2024, 0(3): 91-96.
[13]	王耀, 邵丹丹, 雷炳育. 共沉淀析出-热压技术制备高储能性能复合材料薄膜[J]. 复合材料科学与工程, 2024, 0(3): 97-102.
[14]	张仲香, 刘宝锋, 方晨鑫, 陈文光, 顾育慧, 李军向. 沙戈荒环境下风电叶片中复合材料耐高温性能研究[J]. 复合材料科学与工程, 2024, 0(3): 103-107.
[15]	邓忠, 支亚非, 程家林, 杨文. 太阳能无人机机翼复合材料主梁铺层优化[J]. 复合材料科学与工程, 2024, 0(3): 108-112.