复合材料科学与工程 ›› 2022, Vol. 0 ›› Issue (8): 117-128.DOI: 10.19936/j.cnki.2096-8000.20220828.018

• 综述 • 上一篇    

SiO2气凝胶材料增强技术研究进展

李艳华, 吴一凡*, 韩琦   

  1. 北京玻钢院检测中心有限公司,北京102101
  • 收稿日期:2022-03-21 出版日期:2022-08-28 发布日期:2022-09-27
  • 通讯作者: 吴一凡(1995-),男,硕士研究生,助理工程师,主要从事烧蚀型热防护材料、复合材料检测技术及标准方面的研究,676313839@qq.com。
  • 作者简介:李艳华(1969-),女,工程师,主要从事复合材料检测技术及标准方面的研究。

Research progress on reinforcement technology of silica aerogel materials

LI Yan-hua, WU Yi-fan*, HAN Qi   

  1. Beijing FRP Institute Test Center Co., Ltd., Beijing 102101, China
  • Received:2022-03-21 Online:2022-08-28 Published:2022-09-27

摘要: SiO2气凝胶材料具有独特的纳米网络骨架结构,赋予材料极小的孔径结构、极高的孔隙率;同时气凝胶骨架的纳米微孔具有较为复杂的结构,可以有效阻挡热流的通过,使其具有极低的导热系数。气凝胶骨架主要为Si—O—Si结构,耐高温性能较为良好。SiO2气凝胶在建筑隔热保温、航空航天热防护、吸音降噪、武器装备制造业等领域具有广泛的应用,是国内外热防护材料的主要研发方向之一。然而,SiO2气凝胶纳米网络骨架结构的强度较低、连续性差,纳米孔结构物理化学结合较差、相关产品脆性较大,在外界载荷作用下极易发生骨架结构破坏,很难兼具热防护和承载的双重功能。本文从骨架增强、聚合物增强、第二相增强三个角度,论述了SiO2气凝胶材料骨架增强的研究现状及存在问题。对国内外关于SiO2气凝胶材料骨架增强技术的研究现状及所存在的主要问题进行了总结归纳,为SiO2气凝胶材料骨架增强技术未来的发展提供了思路。

关键词: SiO2气凝胶, 纤维增强, 聚合物增强, 结构增强

Abstract: Silica aerogel has a unique nano-network framework structure, which endows it with extremely high porosity and extremely low density. The complex micro-nano structure of silica aerogel can effectively block thermal convection, making it with extremely low thermal conductivity. Si—O—Si with excellent heat resistance constitutes the main structure of silica aerogel. Silica aerogel has a wide range of applications in building thermal insulation, aerospace thermal protection, sound absorption and noise reduction, weapon equipment manufacturing and other fields. Silica aerogel is one of the main research and development directions of thermal protection materials at home and abroad. However, silica aerogel has the disadvantages of low strength and poor continuity of nano-network skeleton structure, poor physical and chemical combination of nano-pore structure, and high brittleness of related products, which makes it difficult to combine thermal protection and load-bearing. In this paper, from the three perspectives of skeleton reinforcement, polymer reinforcement and second phase reinforcement, the research status and existing problems of silica aerogel reinforcement technology are discussed. This paper summarizes the research status of silica aerogel reinforcement technology at home and abroad, and provides ideas for the future development of silica aerogel framework reinforcement technology.

Key words: silica aerogel, fiber reinforcement, polymer reinforcement, structural reinforcement

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