B4Cp/Al复合材料的界面调控及塑性变形行为研究进展

doi:10.19936/j.cnki.2096-8000.20230428.019

摘要/Abstract

摘要： B¹⁰具有优异的热中子屏蔽性能,B¹⁰含量高、断裂韧性好、可进行塑性变形加工的B₄C_p/Al复合材料大尺寸薄板在乏燃料后处理方面有着广阔的应用前景。但是,随着B₄C颗粒含量的增多,B₄C与Al界面处脆性相增多,导致B₄C_p/Al复合材料的韧性变差,塑性变形能力减弱,后续塑性加工成型性差。因此,制备热中子屏蔽性能好的高硼含量B₄C_p/Al板材的关键是在保证高B₄C颗粒含量的前提下,通过控制B₄C颗粒和Al基体界面反应产物,提高B₄C_p/Al复合材料的韧性和塑性变形能力。本文首先介绍了B₄C_p/Al复合材料的制备方法,重点对浸渗法进行了论述,并介绍了B₄C_p/Al复合材料的塑性变形机制,对热加工温度、应变速率和B₄C_p/Al复合材料界面结构对B₄C_p/Al的塑性变形能力和热轧性能的影响进行了综述。同时,介绍了国内外近年来通过控制浸渗温度、添加合金元素和陶瓷颗粒等方法,实现对B₄C_p/Al复合材料界面成分、结构调控的研究成果。最后,本文对采用浸渗和热轧加工制备用于乏燃料后处理的高硼含量B₄C_p/Al复合材料大尺寸薄板的研究进行了展望。

关键词: 铝基碳化硼, 浸渗, 塑性变形, 热轧, 界面, 复合材料

Abstract: B¹⁰ has excellent thermal neutron shielding performance. B₄C_p/Al composite large size sheet with high B¹⁰ content, good fracture toughness and plastic deformation prosessing has a broad application prospect in the post-processing of spent fuel. However, with the increase of the content of B₄C particles, the brittle phases at the interface between B₄C and Al increase, resulting in poor toughness of B₄C_p/Al composites, weakened the plastic deformation ability, and the subsequent plastic processing formability. Therefore, the key to preparing high boron content B₄C_p/Al sheet with good thermal neutron shielding performance is to improve the plastic deformation capacity and hot rolling performance of B₄C_p/Al composites by controlling the interface reaction products of B₄C particles and Al matrix under the premise of ensuring the high content of B₄C particles. This article first introduces the fabrication method of B₄C_p/Al composite and focusing on infiltration especially. This article also introduces the plastic deformation mechanism of B₄C_p/Al, and reviews the effects of hot working temperature, strain rate and interface structure on the plastic deformation capacity and hot rolling properties of B₄C_p/Al, meanwhile, the recent results about controlling the infiltration temperature, adding alloying elements or ceramic phase to adjust the composition and structure of the B₄C_p/Al interface were introduced. In the end, this article points out the future directions of fabrication and processing of high boron content B₄C_p/Al large size composite sheet for spent fuel reprocessing by infiltration and hot rolling.

Key words: B₄C/Al, infiltration, plastic deformation, hot rolling, interface, composites

中图分类号:

TB332

彭昊恺, 刘瑶, 马东林, 冷永祥. B₄C_p/Al复合材料的界面调控及塑性变形行为研究进展[J]. 复合材料科学与工程, 2023, 0(4): 128-136.

PENG Haokai, LIU Yao, MA Donglin, LENG Yongxiang. Research progress on interface control and plastic deformation behavior of B₄C_p/Al composites[J]. COMPOSITES SCIENCE AND ENGINEERING, 2023, 0(4): 128-136.

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B₄C_p/Al复合材料的界面调控及塑性变形行为研究进展

Research progress on interface control and plastic deformation behavior of B₄C_p/Al composites

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