玻璃钢/复合材料 ›› 2008, Vol. 203 ›› Issue (1): 35-40.

• 产品 工艺 • 上一篇    下一篇

玻璃钢在盐雾环境中腐蚀机制和性能演变规律的试验研究

  

  • 出版日期:2008-01-28 发布日期:2008-01-25
  • 基金资助:

    “十五”国家科技攻关项目子项(ZZ01-08-03-01)

EXPERIMENTS ON CORROSION MECHANISM AND PERFORMANCE EVOLUTION RULE OF GFRP IN SALT STEAM ENVIRONMENT

  • Online:2008-01-28 Published:2008-01-25

摘要:

本文在总结复合材料在海洋的盐雾环境中使用的材料腐蚀理论基础上,分析复合材料发生腐蚀的主要形式和历程,模拟自然环境试验设计不同盐雾温度、不同老化时间下的加速老化试验,通过材料表面形貌、玻璃化转变温度、微观结构的变化来评价玻璃钢在盐雾中的腐蚀性能,着重分析温度、时间对材料腐蚀性能的影响规律|根据中值老化寿命和剩余强度之间的关系式,建立了加速寿命规律模型和寿命预测模型|根据试验中玻璃钢力学性能随老化时间的衰减多数情况下具有一致的规律性,建立了盐雾环境中玻璃钢力学性能随老化时间的衰减三线型模型。试验结果表明,在盐雾环境中,玻璃钢除了可见的外观发生变化外,其玻璃化转变温度、表面巴氏硬度、拉伸强度和弯曲强度均呈现下降趋势,并且随温度的提高和腐蚀时间的延长,性能下降会进一步加大|中值老化寿命和剩余强度之间的关系式能比较好地描述聚合物基复合材料自然老化规律和加速老化规律,力学性能随老化时间的衰减三线型模型能够直观的反映玻璃钢在盐雾环境中加速老化的各个阶段。

关键词: 玻璃钢, 海洋环境, 腐蚀, 加速老化试验

Abstract:

Through collate and summarize the basic corrosion theories of composite materials in salt steam of marine environment,this paper analyzed main corrosion forms and courses of the composite material.It is designed accelerated aging experiments with different salt steam temperature and aging time. Then I evaluated the corrosion of GFRP in the marine environment by analysising the material surface,glass transition temperature,changes in the micro-structure,focused on influence caused by different of temperature and age.Based on the equation of median aging expectancy and the remaining strength,a model of accelerated aging and a model of life prediction were established.According to the consistent attenuation of the mechanical properties of GFRP in aging period,a three linear model of mechanical properties attenuation with aging time in salt steam was established.The results show that besides the exterior changes,the glass transition temperature,the barthel hardness,the tensile strength and...更多 bending strength of GFRP all show a downward trend in salt steam environment.And these will increase with the increasing temperature or extend the time.The equation of median aging expectancy and the remaining strength can describe the rule of natural aging and accelerated aging of polymer matrix composites.The three linear model of mechanical properties attenuation with aging time can directly reflecte every corrosion stages of GFRP in salt steam environment.

Key words: GFRP, marine environment, corrosion, accelerated aging experiment