T300与国产PAN基炭纤维的结构和性能研究

玻璃钢/复合材料 ›› 2009, Vol. 209 ›› Issue (3): 36-40.

T300与国产PAN基炭纤维的结构和性能研究

杨玉蓉¹，杨永生²，华中¹，刘新³

1.吉林师范大学凝聚态物理研究所，吉林四平136000；2.哈尔滨玻璃钢研究院，黑龙江哈尔滨150036；
3.哈尔滨工业大学复合材料与结构研究所，黑龙江哈尔滨150001

出版日期:2009-05-28 发布日期:2009-03-25
作者简介:杨玉蓉（1979）,女,硕士。
基金资助:
吉林省教育厅科研计划项目(200456)

STRUCTURE AND PROPERTIES OF T300 AND DOMESTIC PANBASED CARBON FIBER

Online:2009-05-28 Published:2009-03-25

摘要/Abstract

摘要：

采用WARD、SAXS、RAMAN、XPS等测试技术对T300和国产聚丙烯腈基炭纤维（PANCF）的组织结构及化学组成进行了表征，分析了材料的微观组织结构与宏观性能的关系。结果表明，和T300相比，国产炭纤维的乱层石墨层间距d002略小，微晶尺寸La，Lc略大，微孔尺寸较大，大孔洞所占百分比较多，微孔含量较低。国产炭纤维表面含氧官能团含量较低，为31.35％，表面活性小。

关键词: PAN基炭纤维, 组织结构, 宏观性能, 表面活性

Abstract:

The microstructure， chemical composition of T300 and domestic PANbased carbon fiber（GCF） was studied by means of WARD，SAXS，RAMAN and XPS. Comparing GCF to T300，results show that the layer spacing d002 of GCF is lower than that of T300，both La and Lc of GCF are higher than that of T300.In addition,the size of the pores of GCF is bigger than that of T300，the bigger pore percentage of unit volume of GCF is higher than that of T300，and the micropore content of GCF is lower than that of T300.The content of surface oxygencontained functional groups of GCF is 31.35％,and the surface activity of GCF is lower than that of T300.

中图分类号:

TQ342⁺742

杨玉蓉, 杨永生, 华中, 刘新. T300与国产PAN基炭纤维的结构和性能研究[J]. 玻璃钢/复合材料, 2009, 209(3): 36-40.

YANG Yu-Rong, YANG Yong-Sheng, HUA Zhong, LIU Xin. STRUCTURE AND PROPERTIES OF T300 AND DOMESTIC PANBASED CARBON FIBER[J]. Fiber Reinforced Plastics/Composites, 2009, 209(3): 36-40.

参考文献

［1］ S R Dha Kate,O P Bahl.Effect of carbon fiber surface functional groups on the mechanical properties of carbon composites with HTT［J］.Carbon,2003,41 （7）:11931203.
［2］孙浩伟，李涛.碳纤维及其复合材料在国外军民领域的应用［J］.纤维复合材料，2005，（3）：6567.
［3］何东晓，贾丽霞，王春雨等.碳纤维在机械设备和建筑物上的应用［J］.纤维复合材料，2006，（3）：5558.
［4］邵劲松，刘伟庆.碳纤维在土木工程中的应用［J］.玻璃钢/复合材料，2005,（5）:4144.
［5］沈国柱，徐政，李轶.短切碳纤维复合材料对8mm波吸收性能研究［J］.玻璃钢/复合材料，2006,（3）:1820.
［6］贺福.碳纤维及其应用技术［M］.北京：化学工业出版社，2004.
［7］ M Kaburagi,Y Bin,D Zhu,et al.Small angle X－ray scattering from voids within fibers during the stabilization and carbonization stages［J］.Carbon,2003,41（5）:915926.
［8］ G P Cherepanoy，A S Balankin,V S Ivanova.Fractal fracture mechanicsA review［J］.Engineering Fracture Mechanics,1995,51（6）:9971033.
［9］ C Sauder,J Lamon,R Pailler.The tensile behavior of carbon fibers at high temperatures up to 2400℃ ［J］.Carbon,2004,42（4）：715725.
［10］李东风，王浩静，贺福等.T300和T700炭纤维的结构和性能［J］.新型炭材料,2007，22（1）:5964.
［11］ F Tuinstra,J L Koenig.Raman spectrum of graphite ［J］.J Chem Phys,1970,53（3）:11261130.
［12］ T J hari,A Roid,J Casado.Raman spectroscopic characterization of some commercially available carbon black materials［J］.Carbon,1995,33 （11）:15611565.
［13］ A Sadezky,H Muckenhuber，H Grothe，et al.Raman microspectroscopy of soot and related carbonaceous materials:Spectral analysis and structural information ［J］.Carbon,2005,43（8）:17311742.
［14］ N Melanitis,PL Tetlow,C Galiotis.Characterization of PANbased carbon fibers with laser Raman spectroscopy［J］.J M ater Sci,1996,31 （4）:851860.
［15］ A Cuesta，P Dhamelincourt，J Laureyns,et al.Raman microprobe studies on carbon materials ［J］.Carbon,1994,32（8）:15231532.
［16］郭慧玲，仲伟虹，张佐光等.几种碳纤维的表面状态表征与分析［J］.复合材料学报,2001,18（3）:3842.
［17］ V K Kaushik.Surface characterization of KMnO4 treated carbon fiber precursors using Xray photoelectron spectroscopy［J］.Polymer Testing,2000,19（1）:1725.
［18］ Z R Yue,W Jiang,L Wang,S D Gardner,C U Pittman Jr.Surface characterization of electrochemically oxidized carbon fibers ［J］.Carbon,1999,37（11）:17851796.
［19］ N Dilsiz,J P Wightman.Surface analysis of unsized and sized carbon fibers［J］.Carbon,1999,37（7）:11051114.
［20］ J L Hueso,J P Espinós,A Caballero,et al.XPS investigation of the reaction of carbon with NO,O2,N2 and H2O plasmas ［J］.Carbon,2007，45（1）:8996.
［21］ S Cudzio,A Huczko,M Pakua,et al.Surface properties of carbons obtained from hexachlorobenzene and hexachloroethane by combustion synthesis ［J］.Carbon,2007.,45（1）:103109.
［22］王明先，王荣国，刘文博.国产高性能碳纤维组织结构表征与性能分析［J］.玻璃钢/复合材料，2007（1）:2832.