玻璃钢/复合材料 ›› 2009, Vol. 209 ›› Issue (5): 23-26.
• 基础研究 • 上一篇 下一篇
出版日期:
发布日期:
作者简介:
Online:
Published:
摘要:
采用旋转流变仪研究了增稠剂的种类和用量、增稠温度以及填料种类等对不饱和聚酯树脂(UP)增稠体系粘度的影响,分别通过酸值滴定和红外分析等手段探讨了MgO和MDI的增稠机理,结果表明,四种增稠剂的增稠速度不同,其中MgO最快;增加增稠剂的用量均可加快增稠速度,增稠速度也随增稠温度的增加而加快;填料的加入使得体系的粘度迅速增大,并且不同种类的填料对体系粘度的影响不同,与CaCO3相比,ATH使体系的粘度增加更多。因此工业生产中要综合考虑各方面因素,以获得合适的增稠工艺。
关键词: 不饱和聚酯, 增稠剂, 增稠机理, 增稠速度
Abstract:
In this paper, the effects of the type and content of thickening agents, thickening temperature and the type of filler on the viscosity of unsaturated polyester resin were studied by Physica MCR 301 rheometer. Otherwise, the thickening mechanisms of MgO and MDI were studied by acid value titration and infrared analysis respectively. The research results showed that,four kinds of thickening agents had different thickening rates, in which MgO was the fastest. As the content of thickening agents increased, the thickening rate increased. The thickening rate also increased with the increasing of the thickening temperature. The addition of fillers made viscosity increase, and different fillers had different effects, compared to CaCO3,the effect of ATH was bigger at the same content. Therefore, many factors should be considered to acquire appropriate thickening process in industrial production.
Key words: unsaturated polyester, thickening agent, thickening mechanism, thickening rate
张兰芬, 吴盾, 刘春林. 不饱和聚酯树脂增稠特性的研究[J]. 玻璃钢/复合材料, 2009, 209(5): 23-26.
ZHANG Lan-Fen, WU-Dun, Liu-Chun-Lin. STUDY ON THICKENING CHARACTERISTICS OF UNSATURATED POLYESTER RESIN[J]. Fiber Reinforced Plastics/Composites, 2009, 209(5): 23-26.
0 / / 推荐
导出引用管理器 EndNote|Ris|BibTeX
链接本文: http://1.203.92.7:8080/blgfhcl/CN/
http://1.203.92.7:8080/blgfhcl/CN/Y2009/V209/I5/23
[1] 张玉军.SMC中不饱和聚酯增稠及固化行为的研究[D] .哈尔滨:哈尔滨理工大学,2002 [2] 张林文,张德镛,杜志花.超级分散氧化镁对SMC/BMC树脂糊粘度的影响[J].玻璃钢/复合材料,2001,(2):2931 [3] 林茂青,张玉军,刘胜平.SMC中不饱和聚酯树脂增稠及贮存性能的研究[J].纤维复合材料,2002,(3):1416. [4] 赵大伟,刘义红,张玉军等.端异氰酸酯基PU增稠端羟基不饱和聚酯SMC的研究[J].纤维复合材料,2003,(2):2022 [5] Reiko Saito, WaiMing J. Kan , L. James Lee. Thickening behaviour and shrinkage control of low profile unsaturated polyester resins[J]. Polymer, 1996, 37(16):35673576. [6] YuenYuen Chiu, Reiko Saito , L. James Lee. Modification of unsaturated polyester resins for viscosity control[J]. Polymer, 1996, 37 (11): 21792190. [7] Mangeng Lu, Mija Shim, Sangwook. Reaction mechanism of an unsaturated polyester system containing thickeners[J]. European Polyester Journal, 2001, 37: 10751078. [8] Nowaczek. W, Kroli Kowski.W. The effect of chemical thickening of polyester moulding compounds on their porperties[J]. Polimery, 1990, 135(12): 2630. [9] 梁苏旦.改进不饱和聚酯树脂的增稠特性[J].热固性树脂,1995,10(4):2728. [10] 金柏青.SMC技术的最新进展[J].玻璃钢/复合材料,1992,(1):4346. [11] 宋中键,王琻,卢萍.UP树脂光增稠研究[J].玻璃钢/复合材料,1997,(1):1315. [12] 不饱和聚酯树脂酸值的测定[S].GB 289582. [13] 刘雄亚,谢怀勤.复合材料工艺及设备[M].武汉:武汉工业大学出版社,1997:8296. [14] 黄家康.聚酯模塑料生产与成型工艺[M].北京:化学工业出版社,2002:5463 [15] 沈开猷.不饱和聚酯树脂及其应用[M].北京:化学工业出版社,1988:266269. [16] 扬四海.SMC制备中树脂糊的粘度控制[J].玻璃钢/复合材料,1997:(4):1112