含硅芳炔树脂的热氧化降解动力学研究

复合材料科学与工程 ›› 2013, Vol. 0 ›› Issue (2): 34-38.

含硅芳炔树脂的热氧化降解动力学研究

池铁, 齐会民^*, 黄发荣, 杜磊

华东理工大学材料科学与工程学院,特种功能高分子材料及相关技术教育部重点实验室,上海200237

收稿日期:2012-02-07 发布日期:2022-03-17
通讯作者: 齐会民,qihm@ecust.edu.cn。
作者简介:池铁(1986-),男,硕士研究生,主要从事耐高温树脂及其复合材料研究。本文作者还有张玲玲和郭康康。
基金资助:
国家自然科学基金(90816021)

THERMAL OXIADATIVE DEGRADATION KINETICS OF SILICON-ARYLACETYLENE-CONTAINING RESIN

CHI Tie, QI Hui-min^*, HUANG Fa-rong, DU Lei

Key Laboratory for Specially Functional Polymer Materials and Related Technologies of Ministry of Education,School of Materials Science and Engineering,East China University of Science and Technology,Shanghai 200237,China

Received:2012-02-07 Published:2022-03-17

摘要/Abstract

摘要： 含硅芳炔树脂是一种新型的耐高温热固性树脂,具有优异的耐热性能、优良的介电性能、高温力学性能和优异的工艺性能,广泛应用于航空航天、电子信息领域。本文用热失重方法(TGA) 研究了含硅芳炔树脂的热氧化降解动力学。结果显示含硅芳炔树脂的热氧化降解过程分为三个阶段,热氧化增重阶段、热氧化降解阶段Ⅰ、热氧化降解阶段Ⅱ。采用Ozawa 和Kissinger 方法分析了含硅芳炔树脂热氧化降解的三个阶段的活化能、反应级数、频率因子等动力学参数。

关键词: 含硅芳炔树脂, 热氧化, 降解动力学

Abstract: Silicon-arylacetylene-containing resin (PSA-R) offers excellent high-temperature resistance,low dielectric constant,high-temperature mechanical property and easy processability. The kinetics of the thermal oxidative degradation of silicon-arylacetylene-containing resin was investigated by thermogravimetric analysis (TGA) under air. The thermal oxidative degradation of PSA-R had three different processes: thermal oxidation of unsaturated chain,thermal oxidative degradation of end-,side-chain scission and main-chain. The corresponding kinetic parameters include activation energy,pre-exponential factor and empirical order of the thermal oxidative degradation stages were evaluated by using Ozawa and Kissinger metnods,respectively.

Key words: silicon-containing arylacetylene resin, thermal oxidative, kinetics

中图分类号:

TB332
TQ323

池铁, 齐会民, 黄发荣, 杜磊. 含硅芳炔树脂的热氧化降解动力学研究[J]. 复合材料科学与工程, 2013, 0(2): 34-38.

CHI Tie, QI Hui-min, HUANG Fa-rong, DU Lei. THERMAL OXIADATIVE DEGRADATION KINETICS OF SILICON-ARYLACETYLENE-CONTAINING RESIN[J]. COMPOSITES SCIENCE AND ENGINEERING, 2013, 0(2): 34-38.

参考文献

[1] Itoh M,Mitsuzuka M,Iwata K, et al. A novel synthesis and extremely high thermal stability of poly[(phenylsily1ene) ethynylene-l,3-phenyleneethynylene][J]. Macromolecules, 1994, 27(26): 7917-7919.
[2] Itoh M,Inoue K,Iwata K. New highly heat-resistant polymer containing silicon: poly(silylene-ethynylenephenyleneethy-nylene) s[J]. Macromolecules,1997,30: 694-701.
[3] Itoh M,Kobayashi M,Ishikawa J. Dehydrogenative coupling reactions between a monosubstituted alkyne and monosilane in the presence of lithium aluminum hydride[J]. Organometallics,1997,16: 3068-3070.
[4] Bavat P,Jousse F,Delnaud L,Levassort C. Synthesis and Properties of New Proeessable Type Polyarylaeetylenes[J]. International SAMPE Sym posium and Exhibition,2000,46: 134-144.
[5] 严浩,齐会民,黄发荣. 新颖含硅芳基多炔树脂的合成与性能[J]. 石油化工,2004,33(9): 880-883.
[6] 张玲玲,高飞,周围,张健,黄发荣,杜磊. 含硅氢基团甲基芳炔树脂的合成及表征[J]. 过程工程学报, 2009,9(3): 574-579.
[7] 高金淼,齐会民,张健,黄发荣,杜磊. 新型含硅芳炔树脂及其复合材料的性能[J]. 化工新型材料,2008,36(12): 45-47, 56.
[8] 齐会民,王春兰,高金淼,黄发荣,杜磊. RTM 用含硅芳炔树脂的流变特性与固化反应动力学[J]. 玻璃钢/复合材料,2009,(6): 62-66.
[9] 徐美玲,石松,王禹慧,张玲玲,王春兰,齐会民,扈艳红,周燕,黄发荣,杜磊. 含硅芳炔树脂热裂解行为及动力学[J]. 玻璃钢/复合材料,2010,(6): 35-39.
[10] 陈麒,倪礼忠. 新的耐高温含硅聚合物-聚硅二乙炔基苯[J]. 玻璃钢/复合材料, 1998,(5): 16-18.
[11] Sun J. T.,Huang Y. D.,Gong G. F.,Cao H. L.. Thermal degradation kinetics of poly (methylphenyl-siloxane) containing methacryloyl groups[J]. Poymer Degradation and Stability,2006, 91: 339-346.
[12] Girish Deshpande,Mary E. Rezac. Kinetic aspects of the thermal degradation of poly(dimethyl siloxane) and poly(dimethyl diphenyl siloxane)[J]. Poymer Degradation and Stability,2002,7 6: 17-24.
[13] 黄剑清,潘安健. 硼改性酚醛泡沫的耐高温性能[J]. 玻璃钢/复合材料,2007,197(6): 26-28.
[14] Yeng-Fong Shih,Ru-Jong Jeng. Thermal degradation behavior and kinetic analysis of unsaturated polyester-based composites and IPNs by conventional and modulated thermogravimetric analysis[J]. Poymer Degradation and Stability,2006,9 1: 823-831.
[15] Mu-Hoe Yang. The thermal degradation of acrylonitrile-butadienestyrene terpolymer under various gas conditions[J]. Polymer Testing, 2000,19: 105-110.
[16] Ahmad Reza Bahramian,Mehrdad Kokabi,Mohammad Hossein Navid Famili,Mohammad Hossein Beheshty. Ablation and thermal degradation behavior of a composite based on resol type phenolic resin: Process modeling and Experimental[J]. Polymer,2006, 47: 3661-3673.
[17] 李建伟,尹昌平,曾竟成,代晓青. RTM 成型石英/钡酚醛耐烧蚀复合材料及其性能研究[J]. 玻璃钢/复合材料,2009,206(3): 41-44.
[18] Richard E. Lyon. Pyrolysis kinetics of char forming polymers[J]. Polymer Degradation and Stability,1998,61: 201-210.
[19] 陈洁,易长海,邹汉涛. 水性环氧树脂制备复合材料的热性能研究[J]. 玻璃钢/复合材料, 2010,(4): 46-48.