聚苯胺/钯纳米复合材料的原位还原法制备及表征

复合材料科学与工程 ›› 2013, Vol. 0 ›› Issue (6): 53-56.

聚苯胺/钯纳米复合材料的原位还原法制备及表征

范竞雄, 杨继萍^*

北京航空航天大学材料科学与工程学院空天材料与服役教育部重点实验室,北京 100191

收稿日期:2012-12-25 出版日期:2013-09-28 发布日期:2022-03-15
通讯作者: 杨继萍(1967-), 女,教授,研究生导师,主要研究方向为高分子及复合材料,jyang@buaa.edu.cn。
作者简介:范竞雄(1988-), 男,硕士研究生,主要研究方向为钯基聚苯胺阳极催化剂。
基金资助:
国家自然科学基金(21174009)

SYNTHESIS AND CHARACTERIZATION OF POLYANILINE-PALLADIUM NANOCOMPOSITES VIA IN-SITU REDUCTION METHOD

FAN Jing-xiong, YANG Ji-ping^*

Key Laboratory of Aerospace Materials and Performance,Ministry of Education,School of Materials Science and Engineering,Beihang University,Beijing 100191,China

Received:2012-12-25 Online:2013-09-28 Published:2022-03-15

摘要/Abstract

摘要： 本文采用原位还原法,利用聚苯胺本身的还原性,对硝酸钯进行了还原和负载,制得了聚苯胺/钯纳米复合材料,考察了掺杂态及脱掺杂态聚苯胺对原位还原反应的影响,通过红外光谱、紫外光谱、扫描电镜和X射线衍射对所得复合材料的结构进行了表征,并用循环伏安法测定了复合材料对甲酸的催化性能。结果表明所制备的复合材料对甲酸具有一定的催化性能,且脱掺杂态聚苯胺复合材料的性能要优于掺杂态聚苯胺复合材料的性能。

关键词: 原位还原法, 聚苯胺, 钯纳米粒子, 复合材料

Abstract: In this paper, polyaniline-palladium nanocomposites, a kind of fuel cell catalysts in the system of formic acid, were successfully prepared by the method of in-situ reduction, in which palladium nitrate was used as the precursor of palladium nanoparticles and polyaniline (PANI) as the reductant and supporter of resulting palladium nanoparticles. The difference between doping PANI and dedoping PANI was studied and the final products were characterized using FT-IR, UV-Vis, X-ray diffraction (XRD), SEM and cyclic voltammetry(CV). The CV results suggested that the composites had the capability of catalyzing formic acid, while the dedoping one showed better performance than the doping one.

Key words: In-situ reduction method, polyaniline, palladium nanoparticles, nanocomposites

中图分类号:

TB332
TB333

范竞雄, 杨继萍. 聚苯胺/钯纳米复合材料的原位还原法制备及表征[J]. 复合材料科学与工程, 2013, 0(6): 53-56.

FAN Jing-xiong, YANG Ji-ping. SYNTHESIS AND CHARACTERIZATION OF POLYANILINE-PALLADIUM NANOCOMPOSITES VIA IN-SITU REDUCTION METHOD[J]. COMPOSITES SCIENCE AND ENGINEERING, 2013, 0(6): 53-56.

参考文献

[1] Wang R.F.,Liao S. J.,Ji S. High performance Pd-based catalysts for oxidation of formic acid[J]. Power Sources,2008,180: 205-208.
[2] Li Y.,Fan X.B.,Qi J. J.,Ji J. Y.,Wang S. L.,Zhang G. L.,Zhang F. B. Palladium Nanoparticle-Graphene Hybrids as Active Catalysts for the Suzuki Reaction[J]. Nano Research,2010,3: 429-437.
[3] Robert D.Morgan,Amin Salehi-khojin,Richard I. Masel. Superior Formic Acid Oxidation Using Carbon Nanotube-Supported Palladium Catalysts[J]. The Journal of Physical Chemistry C,2011,115: 19413-19418.
[4] J. Bedia,J. M. Rosas,J. Rodriguez-Mirasol,T. Cordero.Pd supported on mesoporous actived carbons with high oxidation resistance as catalysts for toluene oxidation[J]. Applied Catalysis B: Environmental,2010,94: 8-18.
[5] Christopher M.A. Parlett,Duncan W. Bruce,Nicole S. Hondow,Adam F. Lee,Karen Wilson. Support-Enhanced Selective Aerobic Alcohol Oxidation over Pd/Mesoporous Silicas[J]. ACS Catalysis,2011,1: 636-640.
[6] 曾效舒,曹东,李文唐. 碳纳米管/聚苯胺复合材料分散性和界面特点[J]. 纤维复合材料,2004,1: 24-27.
[7] 张超灿,宋丽娜,孙江勤,袁坚,单松高,程金树. 有机硅改性聚甲基丙烯酸甲酯-聚苯胺复合材料的制备及其电致变色性能研究[J]. 2001,11-15.
[8] 钟平,黄建军. 聚苯胺/聚乙烯醇微乳液导电涂料的研制及其性能的测试[J]. 玻璃钢/复合材料,2009,58-60.
[9] 黄美荣,李新贵,曾剑锋. 聚苯胺纳米复合材料的特异性能及应用前景[J]. 玻璃钢/复合材料,2004,8-11.
[10] 罗远来,梁振兴,廖世军. 直接甲醇燃料电池阳极催化剂研究进展[J]. 催化学报,2010,31(2): 141-149.
[11] Park Jong-Eun,Park Soo-Gil,Koukitu Akinori,Hatozaki Osamu,Oyama Noboru.Electrochemical and chemical interactions between polyaniline and palladium nanoparticles[J]. Synthetic Metals,2004,141: 265-269.
[12] A. Drelinkiewicz,M. Hasik,S. Quillard,C. Paluszkiewize. Infrared and Raman studies of palladium-nitrogen-containing polymers interactions[J]. Journal of Molecular Structure,1999,511-512: 205-215.
[13] Nie G.R,Zhang L,Cui Y. C. Peraration of Pd nanoparticles deposited on a polyaniline/multiwall carbon nanotubes nanocomposite and their application in the Heck reaction[J]. React Kinet Mech Cat,2012.
[14] M. G. Hosseini,S. Zeynali,M. M. Momeni,R. Najjar.Polyaniline Nanofibers Supported on Titanium as Templates for Immobilization of Pd Nanoparticles: A New Electro-Catalyst for Hydrazine Oxidation[J]. Journal of Applied Polymer Science,2012,124: 4671-4677.
[15] Ibrahim Dodouche,Danns Pereira Barbosa,Maria do Carmo Rangel,Florence Epron. Palladium-tin catalysts on conducting polymers for nitrate removal[J]. Applied Catalysis B: Environmental,2009,93: 50-55.
[16] Gao Y,Chen C.A,Gau H. M,J. A. Bailey,E. Akhadov,D.Williams,Wang H. L. Facile Synthesis of Polyaniline-Supported Pd Nanoparticles and Their Catalytic Properties toward Selective Hydrogenation of Alkynes and Cinnamaldehyde[J]. Chemistry of Materials,2008,20: 2839-2844.
[17] Benjamin J. Gallon,Robert W. Kojima,Richard B. Kaner,Paula L.Diaconescu. Palladium Nanoparticles Supported on Polyaniline Nanofibers as a semi-Heterogeneous Catalyst in Water[J]. Nanoparticle Catalysts,2007,46: 7251-7254.
[18] Yin H.J, Yang J. P. Synthesis of high-performance onedimensional polyaniline nanostructures using dodecylbenzene sulfonic acid as soft template[J]. Materials Letters,2011,55: 850-853.
[19] T. Teranishi and M. Miyake. Size Control of Palladium Nanoparticles and Their Crystal Structures[J]. Chemistry of Materials,1998,10: 594-600.
[20] 翁诗甫. 傅里叶变换红外光谱分析[M]. 北京: 化学工业出版社,2010.