自修复聚合物材料用微胶囊的研究进展

复合材料科学与工程 ›› 2015, Vol. 0 ›› Issue (3): 87-91.

自修复聚合物材料用微胶囊的研究进展

王晴, 李海燕^*, 崔业翔

东北石油大学化学化工学院石油与天然气化工重点实验室,黑龙江大庆 163318

收稿日期:2014-10-20 出版日期:2015-03-28 发布日期:2021-09-13
通讯作者: 李海燕(1980-),女,博士,副教授,主要从事智能聚合物材料的研究,lhy06b@163.com。
作者简介:王晴(1988-),女,硕士研究生,主要从事自修复材料制备及性能方面的研究。
基金资助:
东北石油大学青年基金项目(2012QN113)

RESEARCH PROGRESS OF MICROCAPSULES USED IN SELF-HEALING POLYMER MATERIALS

WANG Qing, LI Hai-yan, CUI Ye-xiang

Provincial Key Laboratory of Oil & Gas Chemical Technology, College of Chemistry & Chemical Engineering,Northeast Petroleum University, Daqing 163318, China

Received:2014-10-20 Online:2015-03-28 Published:2021-09-13

摘要/Abstract

摘要： 自修复材料是一种新型的智能材料。将微胶囊埋植于材料中是实现其自修复的一种方法,也是目前该领域的研究热点之一。本文介绍了微胶囊型自修复的概念和原理,综述了近几年来DCPD型微胶囊、环氧树脂型微胶囊、硅油型微胶囊以及其他微胶囊型自修复的发展状况,并着重介绍了最新研究成果,对微胶囊型自修复材料的研究前景进行了展望。

关键词: 微胶囊, 自修复, 聚合物材料

Abstract: Self-healing material is a new kind of smart materials, the microcapsule embeded in the material is a method to realize the self-healing, and it is also one of the hotspots in this field. This paper introduces the concept and principle of microcapsule type self-healing, summarizes the development of DCPD microcapsules, epoxy resin microcapsules, silicone oil microcapsules and other microcapsules type self-healing in recent years, and emphatically introduces the latest research results, and the prospect of microcapsules type self-healing materials.

Key words: microcapsule, self-healing, polymer materials

中图分类号:

TB332

王晴, 李海燕, 崔业翔. 自修复聚合物材料用微胶囊的研究进展[J]. 复合材料科学与工程, 2015, 0(3): 87-91.

WANG Qing, LI Hai-yan, CUI Ye-xiang. RESEARCH PROGRESS OF MICROCAPSULES USED IN SELF-HEALING POLYMER MATERIALS[J]. COMPOSITES SCIENCE AND ENGINEERING, 2015, 0(3): 87-91.

参考文献

[1] S. R. White, N. R. Sottos, P. H. Geubelle, J. S. Moore, M. R. Kessler, S. R. Sriram, E. N. Brown, S.Viswanathan. Autonomic Healing of Polymer Composite[J]. Nature, 2001, 409: 794-797.
[2] 汪海平, 章明秋, 容敏智. 智能自修复型聚合物基复合材料[J]. 航空制造技术, 2011, (20):92-93.
[3] 罗永平. 自修复微胶囊的合成与应用研究[D]. 广州:华南理工大学, 2011.
[4] 李海燕. 脲醛树脂微胶囊表面改性及对环氧树脂的自修复性能研究[D]. 哈尔滨: 哈尔滨工业大学, 2010.
[5] 吕玲, 袁莉, 梁国正. 聚脲甲醛包覆双环戊二烯微胶囊的热稳定性研究[J]. 工程塑料应用, 2006, 34(3): 48-50.
[6] 李岚, 袁莉, 梁国正, 谢建强. 表面活性剂对聚脲甲醛包覆双环戊二烯微胶囊的影响[J]. 精细化工, 2006, 23(5): 429-434.
[7] 卢玲茹, 范传杰, 周晓东. 聚合物基复合材料自修复微胶囊的制备及形态控制[J]. 化学世界, 2006, 增刊: 122-123.
[8] A.Fereidoon, M.Ghorbanzadeh Ahangari, M.J-ahanshahi. Effect of nanoparticles on the morphology and thermal properties of self-healing poly(urea-formaldehyde) microcapsules[J]. Journal of Pol-ymer Research, 2013, 20(6): 151.
[9] 唐欣欣. 环氧树脂阴离子催化剂型固化剂微胶囊的制备及性能表征[D]. 哈尔滨: 哈尔滨工业大学, 2011.
[10] 倪卓, 杜学晓, 王帅, 梁伟杰, 苏晓敏, 单晓凤. 微胶囊对微胶囊/环氧树脂复合材料增韧作用[J]. 复合材料学报, 2011, 28(4): 63-69.
[11] 廖乐平, 张伟, 赵阳. 仿生自修复环氧树脂涂层制备及性能[J]. 中国表面工程, 2013, 26(4): 88-93.
[12] 谢建强, 梁国正, 袁莉, 张增平. 聚苯乙烯包覆环氧树脂微胶囊的研制[J]. 塑料工业, 2007, 35(3): 64-67.
[13] 郭琼. 环氧树脂微胶囊与咪唑衍生物固化剂自修复材料研究[D]. 哈尔滨: 哈尔滨工业大学, 2010.
[14] 魏铭, 胡巧玲, 董志超, 李艳, 刘朝阳. 涂料用自修复微胶囊的制备工艺研究[J]. 涂料工业, 2012, 42(9): 48-52.
[15] 袁彦超, 容敏智, 章明秋. 三聚氰胺-甲醛树脂包裹环氧树脂微胶囊的制备及表征[J]. 高分子学报, 2008, 5: 472-479.
[16] Qi Li, Siddaramaiah, Nam Hoon Kim, David Huid, Joong Hee Lee. Effects of dual component microcapsules of resin and curi-ng agent on the self-healing efficiency of epoxy[J]. CompositesPart B: Engineering, 2013, 55: 79-85.
[17] 汪海平. 聚砜包覆环氧树脂微胶囊的制备[J].中国塑料, 2013, 27(11): 48-53.
[18] 袁立业. 乙二胺微胶囊的制备与表征[D]. 哈尔滨:哈尔滨工业大学, 2011.
[19] Ding Shu Xiao, Yan Chao Yuan, Min Zhi Rong, Ming Qiu Zha-ng. Hollow polymeric microcapsules: Preparation, characterization and application in holding boron trifluoride diethyl etherate[J]. Polymer, 2009, 50: 560-568.
[20] Li Yuan, Sidi Huang, Aijuan Gu, Guozheng Liang, Feng Chen, Yinghui Hu, Steven Nutt. A cyanateester/microcapsule system with low cure temperature and self-healing capacity[J]. Composites Science and Technology, 2013, 87:111-117.
[21] 邢瑞英, 张秋禹, 艾秋实, 吉志强, 孙九立, 王小强. 反应性乙烯基硅油/聚脲甲醛自修复微胶囊的制备[J]. 材料导报:研究篇, 2009, 23(5): 87-89.
[22] 艾秋实, 张秋禹, 邢瑞英, 张军平. 一步法制备聚脲甲醛包覆反应性乙烯基硅油微胶囊[J]. 中国胶粘剂, 2010, 19(4): 13-16.
[23] 魏文政, 张扬, 林牧春, 刘孝会. 聚脲包覆 KH560硅烷偶联剂微胶囊的制备研究[J]. 表面技术, 2009, 38(2): 55-56.
[24] Mingxing Huang, He Zhang, Jinglei Yang. Synthesis of organic silane microcapsules for self-healing corrosion resistant polymer coatings [J]. Corrosion Science, 2012, 65: 561- 566.
[25] 赵鹏. 金属防腐涂料自修复微胶囊的合成与性能研究[D]. 广州:华南理工大学, 2012.
[26] Rajendra S. Jadhav, Dilip G. Hundiwale, Pramod P. Mahulikar. Synthesis and characterization of phenol-formaldehyde microcap-sules containing linseed oil and its use in epoxy for self-healingand anticorrosive coating [J]. Journal of Applied Polymer Science, 2011, 2911-2916.
[27] C.Suryanarayana, K.Chowdoji Rao, Dhirendra Kumar. Preparation and characterization of microcappsules containing linseed oil and its use in self-healing coatings[J]. Progress in Organic Coatings, 2008, 63: 72-78.
[28] Zhengxian Yang, John Hollar, Xiaodong He, Xianming Shi. A self-healing cementitious composite using oil core/silica gel shell microcappsules[J]. Cement&Concrete Composites, 2011, 33: 506-512.
[29] Jun-Feng Su, Jian Qiu, Erik Schlangen. Stability investigation of self-healing microcapsules containing rejuvenator for bitumen[J].Polymer Degradation and Stability, 2013, 98: 1205-1215.