玻璃钢/复合材料 ›› 2016, Vol. 0 ›› Issue (3): 60-64.

• 应用研究 • 上一篇    下一篇

表面处理工艺对碳纤维复合材料的ILSS及界面形貌的影响

陈秋飞1,戴慧平1*,郭鹏宗1,连峰2   

  1. 1.中复神鹰碳纤维有限责任公司,连云港222069;
    2.中国复合材料集团有限公司,北京100036;
    3.中国建筑材料科学研究总院,北京100024
  • 收稿日期:2015-09-15 出版日期:2016-03-28 发布日期:2016-03-28
  • 通讯作者: 戴慧平(1987-),女,硕士,助理工程师,主要从事碳纤维及其复合材料方面的研究,daicv113@163.com。
  • 作者简介:陈秋飞(1982-),男,高级工程师,硕士,主要从事碳纤维及其复合材料方面的研究。
  • 基金资助:
    中国建筑材料科学研究总院绿色建筑材料国家重点实验室开放基金课题(集束型碳纤维改善混凝土韧性的试验研究)

THE INFLUENCE OF SURFACE TREATMENT PROCESS ON ILSS AND INTERFACEMORPHOLOGY OF CARBON FIBER/RESIN COMPOSITES

CHEN Qiu-fei1, DAI Hui-ping1*, GUO Peng-zong1, LIAN Feng2   

  1. 1.Zhongfu Shenying Carbon Fiber Co., Ltd., Lianyungang 222069, China;
    2.China Composites Group Co., Ltd., Beijing 100036, China;
    3.China Building Marerials Acadermy, Beijing 100024, China
  • Received:2015-09-15 Online:2016-03-28 Published:2016-03-28

摘要: 考查了不同表面处理工艺对碳纤维复合材料层间剪切强度及层面、断面形貌的影响。通过材料实验机测得碳纤维及其复合材料的拉伸强度和层间剪切强度,并通过扫描电镜分析评价不同电导率对复合材料ILSS的影响。结果表明,12ms/cm是表面处理工艺中电导率的较优选择;碳纤维的层间剪切强度随电量的变化符合“层进式物化双效模型”;制备高层间剪切强度碳纤维和复合材料时,较优的电解质是NaOH,较优的电解液浓度为2%,较优的电量为10C/g;本工艺条件下制得的SYT49碳纤维层面形貌与东丽T700G碳纤维相似。

关键词: 表面处理, 电导率, 拉伸强度, 层间剪切强度, 界面形貌, 碳纤维, 复合材料

Abstract: Surface treatment process is one of the most important conditions for preparing high-performance carbon fibers. This article studies the influence of the interlaminar shear strength and cross section and level morphology of carbon fiber/resin composites under different surface treatment process of PAN-based carbon fiber. We tested the tensile strength of carbon fibers and the interlaminar shear strength of its composites. We also analyze and evaluate the influence of different surface production processes on ILSS of carbon fiber/resin composites by SEM. The results show that, the electric conductivity of 12 ms/cm is a better choice in surface treatment technology, interlaminar shear strength is 81.2 MPa of composite materials and the ratio of tensile strength is 1.02% between un-surface treatment and surface treatment carbon fiber. The changes between interlaminar shear strength and electricity of high-performance dry jet wet spinning carbon fibers are conformed to the "layer enter type materialized double model". The better choice of electrolyte is NaOH, the better choice of concentration is 2%, and the better choice of electricity is 10 C/g when preparing high-interlaminar shear strength carbon fiber and composite materials. The level morphology between SYT49 carbon fiber composite materials and T700G are the same under the surface treatment process.

Key words: surface treatment, electrical conductivity, tensile strength, interlaminar shear strength, interface morphology, carbon fiber, composite

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