BF表面改性对BF/竹/木复合材料胶合性能的影响

玻璃钢/复合材料 ›› 2017, Vol. 0 ›› Issue (1): 86-91.

BF表面改性对BF/竹/木复合材料胶合性能的影响

向艳艳, 申士杰^*, 靳婷婷

北京林业大学材料科学与技术学院,木质材料科学与应用教育部重点实验室,北京100083

收稿日期:2016-01-05 出版日期:2017-01-28 发布日期:2017-01-28
通讯作者: 申士杰(1957-),男,教授,主要研究方向为工程木质复合材料,shijies@263.net。
作者简介:向艳艳(1991-),女,在读硕士研究生,主要研究方向为工程木质复合材料。
基金资助:
国家“十二五”863课题“国产碳纤维复合材料压挤成型及其应用技术研究”(2012AA03A204-01)

EFFECT OF THE BF'S SURFACE MODIFICATION ON BF/BAMBOO/WOOD COMPOSITE'S BONDING PROPERTIES

XIANG Yan-yan, SHEN Shi-jie^*, JIN Ting-ting

Key Laboratory of Wood Materials Science and Application, Ministry of Education, College of Materials Science and Technology, Beijing Forestry University, Beijing 100083, China

Received:2016-01-05 Online:2017-01-28 Published:2017-01-28

摘要/Abstract

摘要： 木质复合材料的胶合性能是结构用材使用过程中的重要参数,使用硅烷偶联剂KH550、等离子体(PL)、马来酸酐(MA)、盐酯刻蚀(AE)和上述方法的组合对玄武岩纤维(BF)表面进行改性,以促进玄武岩纤维增强竹木复合材料的胶合性能。研究结果表明,对玄武岩纤维增强表面进行上述方法的组合处理效果较佳,BF/竹/木复合材料胶合性能影响依次为MA550＞PL550＞AE550>KH550。其中:KH550和马来酸酐接枝组合处理后,复合材料的竹-纤维胶层的剪切强度达到8.64 MPa,木-纤维胶层剪切强度达到8.47 MPa;竹-纤维胶层KH550和马来酸酐接枝组合处理后比只经过KH550处理的提高了50.45%,木-纤维胶层无纤维剥离。

关键词: 玄武岩纤维, 复合材料, 马来酸酐, 胶合性能

Abstract: Bonding performance of wood composite material is important parameters in the use of wood composite structural material. In this study, in oder to reinforce the bonding properties of BF/bamboo/wood composite, we use silane coupling agent KH550, plasma (PL), maleic anhydride (MA), salt ester etching (AE) and a combination of the above methods to modify the basalt fiber surface.The results showed the combination treatment on reinforcing the surface of basalt fiber has a better prefermance, and the order of effecting the BF/bamboo/wood composite bonding properties is as follows: MA550>PL550>AE550>KH550. After the KH550 and maleic anhydride-grafted combination treatment, the shear strength of bamboo-fiber layer reached 8.64 MPa, and the shear strength of wood-fiber layer reached 8.47 MPa; MA550 combination treatment increased by 50.45% than individual KH550 treatment, whereas wood-fiber glue had no fiber release.

Key words: basalt fiber, composite materials, maleic anhydride, bonding properities

中图分类号:

TB332

向艳艳, 申士杰, 靳婷婷. BF表面改性对BF/竹/木复合材料胶合性能的影响[J]. 玻璃钢/复合材料, 2017, 0(1): 86-91.

XIANG Yan-yan, SHEN Shi-jie, JIN Ting-ting. EFFECT OF THE BF'S SURFACE MODIFICATION ON BF/BAMBOO/WOOD COMPOSITE'S BONDING PROPERTIES[J]. Fiber Reinforced Plastics/Composites, 2017, 0(1): 86-91.

参考文献

[1] 贺勇, 戈振扬. 竹材性质及其应用研究进展[J]. 福建林业科技, 2009(02): 135-139.
[2] 王小青, 赵行志, 高黎, 等. 竹木复合是高效利用竹材的重要途径[J]. 木材加工机械, 2002(4): 25-27.
[3] 刘珊杉. 竹木复合材料的发展[J]. 林业机械与木工设备, 2012(5): 8-9.
[4] 张齐生. 我国竹材加工利用现状与探讨[J]. 西南林学院学报, 1993,13(4): 24-25.
[5] 张戌社, 宁辰校. 竹/玻璃纤维复合建筑材料及其应用[J]. 建材技术与应用, 2002(2): 6-7.
[6] Dagher HJ, Shaler SM, Lowry C. FRP Reinforced Particleboard[J]. Forest Products Journal, 1985, 35(5): 61-68.
[7] Dagher HJ, Lindyberg R. FRP reinforced wood in bridge applications[J]. 1st RILEM Symposium on Timber Engineering, 1999: 591-598.
[8] Dorey AB, Cheng JJR. Glass fiber reinforced glued laminated wood beams[M]. Edmonton, AB, Canada: Canada-Alberta Partnership Agreement in Forestry, 1996.
[9] 鲍甫成, 张双保, 等. 木材与玻璃纤维复合材料性能改善的研究[J]. 林业科学, 2004, 5(3): 16-21.
[10] 徐正东, 赵俊石, 张双保. 玻璃纤维增强结构用单板层积材热压工艺研究[J]. 林业机械与木工设备, 2012, 40(5): 37-40.
[11] Cui YH, Tao J. Fabrication and mechanical properties of glass fiber-reinforced wood plastic hybrid composites[J]. Journal of Applied Polymer Science, 2009, 112(3): 1250-1257.
[12] 牛磊, 黄英, 张银铃. 高性能纤维增强树脂基复合材料的研究进展[J]. 材料开发与应用, 2012, 27(3): 86-88.
[13] Chen J X, Guan S J, Zhang S H, et al. Development of Basalt Fiber Reinforced Wood-plastic Composite Materials[J]. Advanced Materials Research, 2011, 189: 4043-4048.
[14] 尚宝月, 杨绍斌. 玄武岩纤维聚合物复合材料的研究进展[J]. 化工进展, 2011, 30(8): 1766-1770.
[15] 李伟娜. 酸刻蚀对玄武岩纤维及其复合材料性能研究[D]. 北京: 北京林业大学, 2013.
[16] 靳婷婷, 申士杰, 李静, 等. 低温等离子处理对玄武岩纤维表面及复合材料性能的影响[J]. 玻璃钢/复合材料, 2015(06): 29-35.
[17] Wei B G, Chang Q, Bao C X, et al. Surface modification of filter medium particles with silane coupling agent KH550[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2013, 434(19): 276-280.
[18] Hoh K P, Ishida H, Koenig J L.Spectroscopic studies of the gradient in the silane coupling agent/matrix interface in fiberglass-reinforced epoxy[J]. Polymer composites, 1988, 9(2): 151-157.
[19] Khan R A, Parsons A J, Jones I A, et al. Effectiveness of 3-Aminopropyl-Triethoxy-Silane as a Coupling Agent for Phosphate Glass Fiber-Reinforced Poly (caprolactone)-based Composites for Fracture Fixation Devices[J]. Journal of Thermoplastic Composite Materials, 2011, 24(4): 517-534.
[20] Inagaki N, Tasaka S, Kawai H. Surface modification of Kevlar^ fiber by a combination of plasma treatment and coupling agent treatment for silicone rubber composite[J]. Journal of Adhesion Science & Technology, 1992, 6(2):279-291.
[21] Culler S R,IshidaH,Koenig J L. FT-IR characterization of the reaction at the silane/matrix resin interphase of composite materials[J]. Journal of colloid and interface science, 1986, 109(1): 1-10.
[22] Iglesias J G, Gonzalez-Benito J, Aznar A J, et al. Effect of glass fiber surface treatments on mechanical strength of epoxy based composite materials[J]. Journal of colloid and interface science, 2002, 250(1): 251-260.