不同纳米核壳粒子增韧环氧树脂体系的性能及机理研究

玻璃钢/复合材料 ›› 2018, Vol. 0 ›› Issue (7): 5-11.

• 基础研究 • 下一篇

不同纳米核壳粒子增韧环氧树脂体系的性能及机理研究

王婧^1,2, 薛忠民³, 李刚^1*, 杨小平¹

1.北京化工大学有机无机复合材料国家重点实验室,北京 100029;
2.山东中材汽车复合材料有限公司,淄博 255202;
3.中材科技股份有限公司,北京 100097

收稿日期:2018-04-24 出版日期:2018-07-20 发布日期:2018-07-20
通讯作者: 李刚(1974-),男,教授,博士,主要从事树脂及复合材料方面的研究,ligang@mail.buct.edu.cn。
作者简介:王婧(1985-),女,博士生,主要从事复合材料及光固化树脂体系方面的研究。
基金资助:
国家自然科学基金(U1362205,U156420074);江苏省工业支撑项目(BE2014146-4)

STUDY ON THE PROPERTIES AND MECHANISM OF TOUGHENED EPOXY RESIN SYSTEM WITH DIFFERENT CORE SHELL PARTICLES

WANG Jing^1,2, XUE Zhong-min³, LI Gang^1*, YANG Xiao-ping¹

1.State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
2.Shandong Sinoma Composite Auto Parts Co., Ltd., Zibo 255202, China;
3. Sinoma Science & Technology Co., Ltd., Beijing 100097, China

Received:2018-04-24 Online:2018-07-20 Published:2018-07-20

摘要/Abstract

摘要： 纳米核壳粒子通常为玻璃化转变温度较高的热塑性聚合物包裹橡胶内核结构,其优点在于在树脂固化前后结构不发生明显变化,不会因为固化过程中橡胶相分离不完全影响树脂性能。但是纳米粒子的均匀分散一直是环氧添加剂使用过程中的难题。采用三种不同组成、不同粒径的核壳粒子增韧环氧树脂,采用DDS固化的双酚F树脂基体,制备了一系列耐热性优良的环氧树脂体系。研究通过预制母液分散二步法分散纳米颗粒,解决纳米粒子的均匀分散问题,得到均一增韧体系。增韧后的三种体系均对树脂韧性有很大的提升作用。经力学性能、热力学性能、流变学性能和微观结构性能等测试和分析,优选出最佳的纳米多尺度核壳粒子增韧环氧体系,并阐明了其增韧机理。

关键词: 核壳粒子, 增韧, 环氧树脂, 纳米分散

Abstract: Core-shell particles are usually consist of a high glass transition temperature "shell" and a rubber "core". The advantage is that the core-shell structure does not change during the process of resin curing. But the uniform dispersion of nanoparticles has always been a difficult problem in the use of epoxy additives. In this paper, we adopt three different kinds of core-shell particles with different composition and sizes to toughen bisphenol F epoxy resin matrix to prepare a series of epoxy resin system with excellent heat resistance. The dispersion of nano-particles by two steps pre-dispersing is studied to obtain a uniform system. The toughening systems have great improvement on resin toughness. The mechanical properties, thermo-properties, rheological properties and microstructure properties has been tested and analyzed. A multi-scale core-shell nanoparticles toughening epoxy system was prepared and its toughening mechanism is illustrated.

Key words: core shell particles, toughening, epoxy resin, dispersion

中图分类号:

TB332

王婧, 薛忠民, 李刚, 杨小平. 不同纳米核壳粒子增韧环氧树脂体系的性能及机理研究[J]. 玻璃钢/复合材料, 2018, 0(7): 5-11.

WANG Jing,XUE Zhong-min,LI Gang*,YANG Xiao-ping. STUDY ON THE PROPERTIES AND MECHANISM OF TOUGHENED EPOXY RESIN SYSTEM WITH DIFFERENT CORE SHELL PARTICLES[J]. Fiber Reinforced Plastics/Composites, 2018, 0(7): 5-11.

参考文献

[1] Ratna D, Banthia A K. Rubber toughened epoxy[J]. Macromolecular research, 2004, 12(1): 11-21.
[2] Hwang J F, Manson J, Hertzberg R, et al. Structure-property relationships in rubber-toughened epoxies[J]. Polymer Engineering & Science, 1989, 29(20): 1466-1476.
[3] Wise C, Cook W, Goodwin A. CTBN rubber phase precipitation in model epoxy resins[J]. Polymer, 2000, 41(12): 4625-4633.
[4] Dadfar M R, Ghadami F. Effect of rubber modification on fracture toughness properties of glass reinforced hot cured epoxy composites[J]. Materials & Design, 2013(47): 16-20.
[5] Wetzel B, Rosso P, Haupert F, et al. Epoxy nanocomposites-fracture and toughening mechanisms[J]. Engineering Fracture Mechanics, 2006, 73(16): 2375-2398.
[6] Kunz-Douglass S, Beaumont P W, Ashby M. A model for the toughness of epoxy-rubber particulate composites[J]. Journal of Materials Science, 1980, 15(5): 1109-1123.
[7] Chikhi N, Fellahi S, Bakar M. Modification of epoxy resin using re-active liquid (ATBN) rubber[J]. European Polymer Journal, 2002, 38(2): 251-264.
[8] Bécu-Longuet L, Bonnet A, Pichot C, et al. Epoxy networks toughened by core-shell particles: influence of the particle structure and size on the rheological and mechanical properties[J]. Journal of applied polymer science, 1999, 72(6): 849-858.
[9] Keller A, Chong H M, Taylor A C, et al. Core-shell rubber nanoparticle reinforcement and processing of high toughness fast-curing epoxy composites[J]. Composites Science and Technology, 2017, 147: 78-88.
[10] Lin K, Shieh Y. Toughening of epoxy resins with designed core-shell particles; proceedings of the Abstracts of papers of the american chemical society, F, 1997[C]//Amer Chemical Soc 1155 16th ST, NW, Washington, DC 20036.
[11] Gam K T. Structure-property relationship in core-shell rubber toughened epoxy nanocomposites[D]. Texas A&M University, 2004.
[12] 田兴和, 徐大勇, 肖珅. 纳米级核壳型交联橡胶改性环氧树脂的探讨[J]. 第十二次全国环氧树脂应用技术学术交流会论文集, 2007.
[13] Quan D, Ivankovic A. Effect of core-shell rubber (CSR) nano-particles on mechanical properties and fracture toughness of an epoxy polymer[J]. Polymer, 2015(66): 16-28.
[14] 汪源, 王源升. 不同结构聚合物核壳粒子对环氧树脂的增韧改性[J]. 高分子材料科学与工程, 2012, 28(2): 23-27.
[15] Ngah S A, Taylor A C. Toughening performance of glass fibre composites with core-shell rubber and silica nanoparticle modified matrices[J]. Composites Part A: Applied Science and Manufacturing, 2016, 80: 292-303.
[16] Wang J, Xue Z, LI Y, et al. Synergistically effects of copolymer and core-shell particles for toughening epoxy[J]. Polymer, 2018, 140: 39-46.
[17] Xu H, Tang S, Yang L, et al. Toughening of polycarbonate by core-shell latex particles: Influence of particle size and spatial dis-tribution on brittle-ductile transition[J]. Journal of Polymer Science Part B: Polymer Physics, 2010, 48(18): 1970-1977.
[18] Deng S, Ye L, Friedrich K. Fracture behaviours of epoxy nanocom-posites with nano-silica at low and elevated temperatures[J]. Journal of materials science, 2007, 42(8): 2766-2774.
[19] Johnsen B, Kinloch A, Mohammed R, et al. Toughening mecha-nisms of nanoparticle-modified epoxy polymers[J]. Polymer, 2007, 48(2): 530-541.
[20] Liu D, Li G, Li B, et al. Establishment of multi-scale interface in interlayer-toughened CFRP composites by self-assembled PA-MWNTs-EP[J]. Composites Science and Technology, 2016, 130: 53-62.

不同纳米核壳粒子增韧环氧树脂体系的性能及机理研究

STUDY ON THE PROPERTIES AND MECHANISM OF TOUGHENED EPOXY RESIN SYSTEM WITH DIFFERENT CORE SHELL PARTICLES

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