聚丙烯酸酯热塑性树脂及其真空辅助灌注成型复合材料性能研究

玻璃钢/复合材料 ›› 2019, Vol. 0 ›› Issue (12): 94-100.

聚丙烯酸酯热塑性树脂及其真空辅助灌注成型复合材料性能研究

张平^1,2, 牟书香^1,2*, 朱金春³, Pierre Gerard⁴

1.特种纤维复合材料国家重点实验室,北京102101;
2.中材科技风电叶片股份有限公司,北京102101;
3.阿科玛常熟化学有限公司,江苏215500;
4.Arkema GRL, France64170

收稿日期:2019-02-26 出版日期:2019-12-28 发布日期:2019-12-28
通讯作者: 牟书香(1981-),女,高级工程师,博士,主要从事风电叶片相关材料及工艺方面的研究,mushuxiang@126.com。
作者简介:张平(1990-),女,材料工程师,博士,主要从事风电叶片相关复合材料和工艺方面的研究。

RESEARCH ON PROPERTIES OF POLYACRYLATE THERMOPLASTIC RESIN AND ITS VACUUM-ASSISTED INFUSION GLASS FIBER REINFORCED COMPOSITES

ZHANG Ping^1,2, MU Shu-xiang^1,2*, ZHU Jin-chun³, PIEERE Gerard⁴

1.State Key Laboratory of Special Fiber Composite Material, Beijing 102101, China;
2.Sinomatech Wind Power Blade Co., Ltd., Beijing 102101, China;
3.Arkema Chemical Co., Ltd., Jiangsu 215500, China;
4.Arkema GRL, 64170, France

Received:2019-02-26 Online:2019-12-28 Published:2019-12-28

摘要/Abstract

摘要： 分析了阿科玛聚丙烯酸酯热塑性树脂Elium190M的反应特性,研究了热塑性树脂的基本性能和真空灌注纤维增强热塑性复合材料的力学性能,并与风电叶片行业批量在用的热固性树脂及其真空灌注复合材料性能进行了对比。研究结果表明,聚丙烯酸酯树脂粘度较低,适用期较长,且固化温度较低,固化时间较短,适用于真空辅助灌注成型工艺。纤维增强热塑性复合材料与风电叶片批量在用的热固性复合材料的力学性能相当,同时热塑性树脂Elium190M与其热塑性复合材料之间具有良好的界面性能,表明该热塑性树脂也可以先局部采用预制件成型,然后采用整体一体灌注成型的方式进行大型复合材料制件的制造。

关键词: 聚丙烯酸酯树脂, 热塑性复合材料, 真空辅助灌注成型, 力学性能

Abstract: The reaction characteristics of Arkema polyacrylate thermoplastic resin Elium190M were analyzed, the basic properties of thermoplastic resin and the mechanical properties of the glass fiber reinforced thermoplastic composite by vacuum infusion were studied, and compared with the thermosetting resin and its vacuum infusion glass fiber reinforced composite which is used in batch in wind turbine blade industry. The results show that polyacrylate resin Elium190M has low viscosity, long open time, low curing temperature and short curing time, which is suitable for vacuum assisted resin infusion process. The mechanical properties of glass fiber reinforced thermoplastic composite are comparable to those of thermosetting composite used in batch for manufacturing of the wind turbine blade. At the same time, the interface property between thermoplastic resin Elium190M and its thermoplastic composite material is higher than that of the thermosetting resin used in batch in wind blade, indicating that the thermoplastic resin can also be molded partially by prefabricated parts, then formed large composite parts by integrated infusion molding.

Key words: polyacrylate resin, thermoplastic composites, vacuum assisted resin infusion, mechanical properties

中图分类号:

TB332

张平, 牟书香, 朱金春, Pierre Gerard. 聚丙烯酸酯热塑性树脂及其真空辅助灌注成型复合材料性能研究[J]. 玻璃钢/复合材料, 2019, 0(12): 94-100.

ZHANG Ping, MU Shu-xiang, ZHU Jin-chun, PIEERE Gerard. RESEARCH ON PROPERTIES OF POLYACRYLATE THERMOPLASTIC RESIN AND ITS VACUUM-ASSISTED INFUSION GLASS FIBER REINFORCED COMPOSITES[J]. Fiber Reinforced Plastics/Composites, 2019, 0(12): 94-100.

参考文献

[1] 申桂英. 高性能热塑性塑料的品种与市场[J]. 精细与专用化学品, 2016, 24(9): 1-4.
[2] 于天淼, 高华兵, 王宝铭, 等. 碳纤维增强热塑性复合材料成型工艺的研究进展[J]. 工程塑料应用, 2018, 46(4): 139-144.
[3] Cherrington R, Goodship V, Meredith J, et al. Producer responsibil-ity: Defining the incentive for recycling composite wind turbine blades in Europe[J]. Energy Policy, 2012, 47: 13-21.
[4] Marsh G. Could thermoplastics be the answer for utility-scale wind turbine blades?[J]. Reinforced Plastics, 2010, 54(1): 31-35.
[5] 牟书香, 杜微. CBT树脂反应特性及其纤维复合材料力学性能的研究[J]. 玻璃纤维/复合材料, 2015(6): 12-17.
[6] Rijswijk K V, Teuwen J J E, Bersee H E N, et al. Textile fiber-reinforced anionic polyamide-6 composites. Part Ⅰ: The vacuum infusion process[J]. Composites: Part A, 2009, 40(1): 1-10.
[7] Rijswijka K V, Bersee H E N, Jager W F, et al. Optimisation of anionic polyamide-6 for vacuum infusion of thermoplastic composites: choice of activator and initiator[J]. Composites: Part A, 2006, 37: 949-956.
[8] Rijswijk K V, Bersee H E N, Beukers A, et al. Optimisation of anionic polyamide-6 for vacuum infusion of thermoplastic composites: influence of polymerisation temperature on matrix properties[J]. Polymer Testing, 2006, 25: 392-404.
[9] 黎敏荣, 薛平, 贾明印, 等. 纤维增强热塑性树脂复合材料成型技术研究进展[J]. 塑料工业, 2016, 44(11): 5-10.
[10] 上海杰事杰新材料股份有限公司. 一种风力发电机叶片用复合材料及其制备方法: 中国 ZL200910052516.X[P]. 2009-06-04.
[11] Garate J, Solovitz S A, Kim D. A preliminary study on small thermoplastic composite wind turbine blade design and fabrication[C]//ASME 2015 International Mechanical Engineering Congress and Exposition. Houston. Texas: 2015: 13-19.
[12] Rijswijk K V, Bersee H E N. Reactive processing of textile fiber-reinforced thermoplastic composites-An overview[J]. Composites: Part A, 2007, 38: 666-681.
[13] Murray R E, Snowberg D, Berry D, et al. Manufacturing a 9-Meter Thermoplastic Composite Wind Turbine Blade[C]//American Society for Composites 32nd Technical Conference. West Lafayette, Indiana: 2017: 23-25.
[14] Murray R E, Jenne S, Snowberg D, et al. Techno-Economic analysis of a Megawatt-Scale thermoplastic resin wind turbine blade[J]. Renewable Energy (2018), DOI: 10.1016/j.renene.2018.07.032.
[15] Kawamura A, Kuromoto M, Iwai T. Evaluation of the setting shrinkage of MMA polymer concrete[J]. American Concrete Institue, 1998, SP-179: 731-745.