玻璃钢/复合材料 ›› 2019, Vol. 0 ›› Issue (2): 69-74.

• 应用研究 • 上一篇    下一篇

碳纳米管环氧树脂复合材料的拉敏性研究

田长进, 管延华, 葛智*, 高杰   

  1. 山东大学土建与水利学院,济南250061
  • 收稿日期:2018-05-25 出版日期:2019-02-25 发布日期:2019-02-28
  • 通讯作者: 葛智(1977-),男,教授,博士,主要从事道路工程材料方面的研究,zhige@sdu.edu.cn。
  • 作者简介:田长进(1994-),男,硕士研究生,主要从事道路工程材料方面的研究。
  • 基金资助:
    教学部留学回国人员科研启动基金(20131792)

STUDY ON PULL SENSITIVITY OF CARBON NANOTUBES EPOXY COMPOSITES

TIAN Chang-jin, GUAN Yan-hua, GE Zhi*, GAO Jie   

  1. School of Civil Engineering, Shandong University, Jinan 250061, China
  • Received:2018-05-25 Online:2019-02-25 Published:2019-02-28

摘要: 碳纳米管是近年来新兴起的具有优异力学性能和电学性能的材料。向环氧树脂中加入碳纳米管可以制成具有机敏性能的复合材料。试验采用两极法,通过改变碳纳米管的浓度确定了碳纳米管环氧树脂复合材料的渗流阈值;研究了温度和湿度对复合材料导电性能的影响;同时采用循环荷载逐级加载的加载方式,研究了复合材料的拉敏性能。试验结果表明:碳纳米管环氧树脂复合材料的渗流阈值区间为0.5wt%~1.0wt%,在此区间内,随着碳纳米管掺量增加,碳纳米管环氧树脂复合材料的电阻率下降明显;随着温度的升高和降低,复合材料的电阻变化率也相应地呈现出增加和减小的趋势,环境中的水分对复合材料的电阻率几乎没有影响;与碳纳米管掺量为0.9wt%时,拉敏性开始明显出现,当掺量大于1.2wt%时,拉敏性逐渐消失,当碳纳米管掺量为1wt%时,拉敏性最佳。

关键词: 道路工程, 碳纳米管环氧树脂复合材料, 渗流阈值, 电阻率, 拉敏性

Abstract: Carbon nanotube is an emerging material with excellent mechanical properties and electrical properties in recent years. The addition of carbon nanotubes to epoxy resins can be made into composites with sensing effect. The bipolar method was used to determine the percolation threshold of carbon nanotube epoxy composites by changing the concentration of carbon nanotubes. The effects of temperature and humidity on the electrical conductivity of the composites were investigated. At the same time, the cyclic loading method was used to study the pulling sensitivity of the composite. It was found that the intervals of percolation threshold of carbon nanotubes epoxy resin matrix composites was ranging from 0.5wt% to 0.8wt%. In this interval, with the increase of the amount of carbon nanotubes, the electrical resistivity of the carbon nanotube epoxy composite decreased significantly. As the temperature increases and decreases, the resistivity of the composite material also shows a corresponding increase and decrease. Moisture in the environment has almost no effect on the resistivity of the composite. The pulling sensitivity of the material appears obviously when the amount of carbon nanotubes is 0.9wt% and the pulling sensitivity fades away when the amount of carbon nanotubes is 1.2wt%. It is proved that the pulling sensitivity of the material is the best when the amount of carbon nanotubes is 1.0wt%.

Key words: roadwork, carbon nanotube epoxy composites, the percolation threshold, resistivity, the pulling sensitivity

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