纤维增强树脂基复合材料多尺度界面模拟研究与进展

复合材料科学与工程 ›› 2020, Vol. 0 ›› Issue (11): 116-122.

纤维增强树脂基复合材料多尺度界面模拟研究与进展

李崇瑞^1,2, 高聪³, 史鹏程^2*, 颜春²

1.上海大学材料科学与工程学院,上海200444;
2.浙江省机器人与智能制造装备技术重点实验室,中国科学院宁波材料技术与工程研究所,宁波315201;
3.重庆长安汽车股份有限公司,重庆400023

收稿日期:2019-12-18 出版日期:2020-11-28 发布日期:2020-11-28
通讯作者: 史鹏程(1992-),男,博士,主要从事复合材料多尺度结构设计方面的研究,shipengcheng@nimte.ac.cn。
作者简介:李崇瑞(1997-),女,硕士研究生,主要从事复合材料界面方面的研究。本文作者还有徐海兵²,祝颖丹²,郭启涛²。
基金资助:
国家自然科学基金(U1809218,U1864211,51803225);中科院战略性先导专项A(XDA-Y04-02-01);宁波市科技创新2025重大专项(2019B10118,2019B10112);宁波市自然科学基金(2019A610146)

MULTI-SCALE INTERFACE SIMULATION RESEARCH AND DEVELOPMENT OF FIBER REINFORCED RESIN COMPOSITES

LI Chong-rui^{1, 2}, GAO Cong³, SHI Peng-cheng^2*, YAN Chun²

1. College of Materials Science and Engineering, Shanghai University, Shanghai 200444, China;
2. Zhejiang Key Laboratory of Robotics and Intelligent Manufacturing Equipment Technology,Ningbo Institute of Material Technology ＆ Engineering, CAS, Ningbo 315201, China;
3. Chongqing Changan Automobile Co., Ltd., Chongqing 400023, China

Received:2019-12-18 Online:2020-11-28 Published:2020-11-28

摘要/Abstract

摘要： 纤维增强树脂基复合材料作为轻量化结构材料,被广泛应用在各行各业,其界面设计与调控研究也受到人们的广泛关注。然而,传统的实验表征很难解释复杂的平衡态/非平衡态界面作用机理,计算机模拟技术作为其补充,在构效关系可视化方面展现了强大的优越性。本文从微观、宏观以及跨尺度三个方面综述了纤维增强树脂基复合材料界面的建模方法和作用机理及其对材料力学性能、热力学性能、动力学性能等的影响,并提出了计算机模拟技术在未来高性能复合材料研发中的指导意义和发展趋势。

关键词: 复合材料界面, 分子模拟, 有限元模拟, 多尺度模拟

Abstract: Nowadays, fiber reinforced resin matrix composites are widely applied in various industries as lightweight structural materials, and the design and research of interface have also attracted people's widespread attention as the Achilles' heel of composite materials. The traditional experimental characterization methods are difficult to explain the complex equilibrium/non-equilibrium interface interaction mechanism, but computer simulation technology shows strong superiority in the visualization of interface interaction mechanisms and the description of quantitative structure-activity relationship (QSAR). In this paper, the modeling methodology and the mechanism of interface of fiber reinforced resin composites and its effect on mechanical properties, thermodynamic properties and kinetic properties of materials are in hierarchical order, including perspectives from microscale, macroscale, and cross-scale, and this article proposes the guiding significance of computer simulation technology for cross-scale constitutive parameters, nonlinear friction dissipation mechanisms, high strengthening and toughening mechanisms, and high-throughput prediction and screening which represent the trends in future development of high-performance composites.

Key words: composite, microscopic simulation, macroscopic simulation, cross-scale simulation

中图分类号:

TB332

李崇瑞, 高聪, 史鹏程, 颜春. 纤维增强树脂基复合材料多尺度界面模拟研究与进展[J]. 复合材料科学与工程, 2020, 0(11): 116-122.

LI Chong-rui, GAO Cong, SHI Peng-cheng, YAN Chun. MULTI-SCALE INTERFACE SIMULATION RESEARCH AND DEVELOPMENT OF FIBER REINFORCED RESIN COMPOSITES[J]. Composites Science and Engineering, 2020, 0(11): 116-122.

参考文献

[1]张文卿, 李肇晨, 吴天宇, 等. 环氧树脂及其复合材料交联结构和宏观性能的分子模拟研究与进展. 复合材料学报, 2019, 36(2): 269-276.
[2]DONG L B, HOU F, LI Y, et al. Preparation of continuous carbon nanotube networks in carbon fiber/epoxy composite. Composites Part A: Applied Science and Manufacturing, 2014, 56: 248-255.
[3]LI M, GU Y Z, LIU H, et al. Investigation the interphase formation process of carbon fiber/epoxy composites using a multiscale simulation method. Composites Science and Technology, 2013, 86: 117-121.
[4]AHMADI M, MASOOMI M, SAFI S, et al. Interfacial evaluation of epoxy/carbon nanofiber nanocomposite reinforced with glycidyl methacrylate treated UHMWPE fiber. Journal of Applied Polymer Science, 2016, 133(31): 1-10.
[5]ZHOU Y H, FAN M Z, CHEN L H. Interface and bonding mechanisms of plant fibre composites: An overview. Composites Part B: Engineering, 2016, 101: 31-45.
[6]LEE S H, WANG S Q, PHARR G M, et al. Evaluation of interphase properties in a cellulose fiber-reinforced polypropylene composite by nanoindentation and finite element analysis. Composites Part A: Applied Science and Manufacturing, 2007, 38(6): 1517-1524.
[7]WANG X Q, AWAN I S, CHEN G Y, et al. Molecular dynamics simulations of interfacial adhesion between carbon fibers and various epoxies/hardeners and its calorimetric validation. Journal of Composite Materials, 2012, 47(8): 1011-1017.
[8]LI C Y, BROWNING A R, CHRISTENSEN S, et al. Atomistic simulations on multilayer graphene reinforced epoxy composites. Composites Part A: Applied Science and Manufacturing, 2012, 43(8): 1293-1300.
[9]KULKARNI M, CARNAHAN D, KULKARNI K, et al. Elastic response of a carbon nanotube fiber reinforced polymeric composite: A numerical and experimental study. Composites Part B: Engineering, 2010, 41(5): 414-421.
[10]WU G P, LI D H, YANG Y, et al. Carbon layer structures and thermal conductivity of graphitized carbon fibers. Journal of Materials Science, 2011, 47(6): 2882-2890.
[11]ZHANG B M, YANG Z, SUN X Y, et al. A virtual experimental approach to estimate composite mechanical properties: Modeling with an explicit finite element method. Computational Materials Science, 2010, 49(3): 645-651.
[12]SUBRAMANIAN N, KOO B, VENKATESAN K R, et al. Interface mechanics of carbon fibers with radially-grown carbon nanotubes. Carbon, 2018, 134: 123-133.
[13]VARSHNEY V, ROY A K, BAUR J W. Modeling the role of bulk and surface characteristics of carbon fiber on thermal conductance across the carbon-fiber/matrix interface. ACS Applied Materials & Interface, 2015, 7(48): 26674-26683.
[14]SHIOYA M, HAYAKAWA E, TAKAKU A. Non-hookean stress-strain response and changes in crystallite orientation of carbon fibres. Journal of Materials Science, 1996, 31(17): 4521-4532.
[15]STOFFELS M T, STAIGER M P, BISHOP C M. Reduced interfacial adhesion in glass fibre-epoxy composites due to water absorption via molecular dynamics simulations. Composites Part A: Applied Science and Manufacturing, 2019, 118: 99-105.
[16]FAN H B, YUEN M M. Material properties of the cross-linked epoxy resin compound predicted by molecular dynamics simulation. Polymer, 2007, 48(7): 2174-2178.
[17]WU C F, XU W J. Atomistic molecular modelling of crosslinked epoxy resin. Polymer, 2006, 47(16): 6004-6009.
[18]YANG S Y, QU J M. Computing thermomechanical properties of crosslinked epoxy by molecular dynamic simulations. Polymer, 2012, 53(21): 4806-4817.
[19]MÄDER E, GAO S L, PLONKA R. Enhancing the properties of composites by controlling their interphase parameters. Advanced Engineering Materials, 2004, 6(3): 147-150.
[20]XU P, YU Y H, GUO Z J, et al. Evaluation of composite interfacial properties based on carbon fiber surface chemistry and topography: Nanometer-scale wetting analysis using molecular dynamics simula-tion. Composites Science and Technology, 2019, 171: 252-260.
[21]SHARMA S, CHANDRA R, KUMAR P, et al. Mechanical proper-ties of carbon nanofiber reinforced polymer composites-molecular dynamics approach. Jom, 2016, 68(6): 1717-1727.
[22]JU S P, CHEN C C, HUANG T J, et al. Investigation of the structural and mechanical properties of polypropylene-based carbon fiber nanocomposites by experimental measurement and molecular dynamics simulation. Computational Materials Science, 2016, 115: 1-10.
[23]CHINKANJANAROT S, RADUE M S, GOWTHAM S, et al. Multiscale thermal modeling of cured cycloaliphatic epoxy/carbon fiber composites. Journal of Applied Polymer Science, 2018, 135(25): 1-10.
[24]CHINKANJANAROT S, TOMASI J M, KING J A, et al. Thermal conductivity of graphene nanoplatelet/cycloaliphatic epoxy composites: Multiscale modeling. Carbon, 2018, 140: 653-663.
[25]LI M, GU Y Z, LI Y X, et al. Competition of diffusion and crosslink on the interphase region in carbon fiber/epoxy analyzed by multiscale simulations. Journal of Applied Polymer Science, 2014, 131(7): 1-7.
[26]COX H L. The elasticity and strength of paper and other fibrous materials. British Journal of Applied Physics, 1952, 3(3): 7.
[27]陈玉丽, 马勇, 潘飞, 等. 多尺度复合材料力学研究进展. 固体力学学报, 2018, 39(1): 1-67.
[28]ZHAO Q, QIAN C C, HARPER L T, et al. Finite element study of the microdroplet test for interfacial shear strength: Effects of geometric parameters for a carbon fibre/epoxy system. Journal of Composite Materials, 2017, 52(16): 2163-2177.
[29]SCHIFFER A, TAGARIELLI V L. Predictions of the interlaminar tensile failure of a carbon/epoxy composite laminate. Composite Structures, 2015, 133: 997-1008.
[30]LIU H, LI M, LU Z Y, et al. Multiscale simulation study on the curing reaction and the network structure in a typical epoxy system. Macromolecules, 2011, 44(21): 8650-8660.
[31]QI Z C, LIU Y, CHEN W L. An approach to predict the mechanical properties of CFRP based on cross-scale simulation. Composite Structures, 2019, 210: 339-347.