水溶性环氧上浆剂对碳纤维复合材料性能影响

复合材料科学与工程 ›› 2020, Vol. 0 ›› Issue (11): 32-36.

水溶性环氧上浆剂对碳纤维复合材料性能影响

柴进¹, 孔海娟^1*, 张新异¹, 余木火²

1.上海工程技术大学材料工程学院,上海201620;
2.东华大学轻质结构复合材料上海市重点实验室,上海201620

收稿日期:2019-12-05 出版日期:2020-11-28 发布日期:2020-11-28
通讯作者: 孔海娟(1985-),女,讲师,博士,主要研究方向为高性能纤维及其复合材料,konghaijuan@sues.edu.cn。
作者简介:柴进(1992-),男,研究生,主要研究方向为碳纤维复合材料。
基金资助:
国家自然基金青年基金项目(51603120);纤维材料改性国家重点实验室资助课(LK1602)

EFFECT OF WATERBORNE EPOXY SIZING AGENT ON PROPERTIES OF CARBON FIBER COMPOSITES

CHAI Jin¹, KONG Hai-juan^1*, ZHANG Xin-yi¹, YU Mu-huo²

1. School of Materials Engineering, Shanghai University of Engineering Science, Shanghai 201620, China;
2. Shanghai Key Lab of Lightweight Composite, Donghua University, Shanghai 201620, China

Received:2019-12-05 Online:2020-11-28 Published:2020-11-28

摘要/Abstract

摘要： 以邻苯二甲酸酐、聚乙二醇2000和环氧树脂E51为原料,制备了水性环氧树脂型上浆剂,使用真空袋成型工艺制备了碳纤维环氧树脂复合材料。分别从热稳定性、接触角表面自由能、碳纤维表面形貌及其复合材料断面形貌和力学性能等方面研究了上浆后的碳纤维环氧复合材料性能。结果表明:上浆剂分解温度在300 ℃左右时,上浆后的碳纤维热稳定性好;与水的接触角从71.4°降低到65.1°,表面自由能从32.2 mN/m增加到了38.9 mN/m;其环氧树脂复合材料层间剪切强度(ILSS)在上浆质量分数为6wt%时达到最大值(88.6 MPa),相比未上浆碳纤维(80.3 MPa)提高了10.3%。

关键词: 碳纤维, 上浆剂, 复合材料, 界面性能

Abstract: A kind of aqueous epoxy resin sizing agent was made by the reaction of phthalic anhydride, polyethylene glycol 2000 and epoxy resin E51. Carbon fiber epoxy resin composite material was prepared by the way of vacuum bag molding process. The properties of the carbon fiber epoxy composites after sizing were estimated by thermal stability, the free energy of the contact angle surface, the surface and composite material section morphology, and interlaminar shear strength (ILSS). The results show that carbon fibers were successfully modified by sizing agent, the decomposition temperature of the sizing agent is about 300 ℃; the contact angle with water decreased from 71.4° to 65.1°, and the surface free energy increased from 32.2 mN/m to 38.9 mN/m; the interlaminar shear strength of the epoxy resin composite reached a maximum value (88.6 MPa) at sizing agent mass fraction of 6wt%, which increased by 10.3% compared with the unsized carbon fiber (80.3 MPa).

Key words: carbon fiber, sizing agent, composite material, interface property

中图分类号:

TB332

柴进, 孔海娟, 张新异, 余木火. 水溶性环氧上浆剂对碳纤维复合材料性能影响[J]. 复合材料科学与工程, 2020, 0(11): 32-36.

CHAI Jin, KONG Hai-juan, ZHANG Xin-yi, YU Mu-huo. EFFECT OF WATERBORNE EPOXY SIZING AGENT ON PROPERTIES OF CARBON FIBER COMPOSITES[J]. Composites Science and Engineering, 2020, 0(11): 32-36.

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