复合材料科学与工程 ›› 2020, Vol. 0 ›› Issue (11): 5-11.

• 基础研究 •    下一篇

表面处理对Vectran增强膜材性能的影响

丁磊1,2, 陈南梁1,2, 王晋熹2, 李贝贝2   

  1. 1.东华大学 高性能纤维及制品教育部重点实验室(B类),上海201620;
    2.东华大学 纺织学院,上海201620
  • 收稿日期:2019-12-18 出版日期:2020-11-28 发布日期:2020-11-28
  • 通讯作者: 蒋金华(1978-),男,副教授,博士,主要研究方向为产业用纺织品、特种编织织造技术与复合材料,jiangjinhua@dhu.edu.cn。
  • 作者简介:丁磊(1995-),男,硕士研究生,主要研究方向为产业用纺织品及复合材料。本文作者还有蒋金华1,2*
  • 基金资助:
    中央高校基本科研业务费专项资金项目(2232020G-02);中国纺织工业联合会应用技术研究项目(J201507);国家级大学生创新创业活动计划项目(201810255001)

EFFECT OF SURFACE TREATMENT ON THE PROPERTIES OF VECTRAN REINFORCED MEMBRANE

DING Lei1,2, CHEN Nan-liang1,2, WANG Jin-xi2, LI Bei-bei2   

  1. 1. Key Laboratory of High Performance Fibers & Products, Ministry of Education,Donghua University, Shanghai 201620, China;
    2. College of Textile, Donghua University, Shanghai 201620, China
  • Received:2019-12-18 Online:2020-11-28 Published:2020-11-28

摘要: 为了增强Vectran基布与水性聚氨酯的界面粘结性能,本文通过对Vectran基布进行碱处理和等离子体处理,研究其对Vectran增强膜材拉伸性能和剥离性能的影响,并采用扫描电子显微镜、接触角表面性能测定仪分析表面处理对Vectran纤维表面形貌和浸润性的影响。研究结果表明:碱处理和等离子处理均能有效提高Vectran纤维界面性能,但对Vectran增强膜材力学性能有不同程度的损伤,其中Vectran基布经20 mol/L碱溶液处理120 min后增强膜材剥离强度增大了70.67%,经10 mol/L碱溶液处理120 min后增强膜材剥离强度增大了29.19%,经等离子体处理6 min后增强膜材剥离强度增大了13.50%;但Vectran基布经20 mol/L碱溶液处理120 min后增强膜材拉伸断裂强度降低了89.99%,经10 mol/L碱溶液处理120 min后增强膜材拉伸断裂强度降低了19.02%,经等离子体处理6 min后增强膜材拉伸断裂强度降低了4.38%。

关键词: Vectran增强膜材, 表面处理, 拉伸性能, 剥离性能, 复合材料

Abstract: In order to enhance the interfacial adhesion between Vectran fibers and water-based polyurethane, the effects of tensile properties and peeling properties of Vectran reinforced membrane materials were investigated by alkali treatment and plasma treatment on Vectran fibers. The effects of surface treatment on the surface morphology and wettability of Vectran fibers were analyzed by scanning electron microscope and contact angle surface property tester. The research results show that both alkaline treatment and plasma treatment can effectively improve the interface properties of Vectran fibers, but they have different degrees of damage to the mechanical properties of Vectran reinforced membrane materials. Among them, the peel strength of Vectran reinforced membrane increased by 70.67% after being treated with 20 mol/L alkali solution for 120 min on base fabric. After 120 min treatment with 10 mol/L alkali solution, the reinforced membrane peel strength increased by 29.19%, and after 6 min with plasma treatment, the reinforced membrane peel strength increased by 13.50%. But tensile strength of the Vectran reinforced membrane materials had been reduced by 89.99% after 120 min treatment with 20 mol/L alkali solution on base fabric. The reinforced membrane tensile strength was reduced by 19.02% after 120 min treatment with 10 mol/L alkali solution, and the reinforced membrane tensile strength was reduced by 4.38% after 6 min of plasma treatment.

Key words: Vectran reinforced membrane, surface treatment, tensile strength, peel strength, composites

中图分类号: