含聚硅氧烷结构的苯并噁嗪对双马来酰亚胺树脂改性研究

复合材料科学与工程 ›› 2020, Vol. 0 ›› Issue (4): 65-71.

含聚硅氧烷结构的苯并噁嗪对双马来酰亚胺树脂改性研究

贾园¹, 刘振¹, 师瑞峰², 杨菊香¹

1.西安文理学院,陕西省表面工程与再制造重点实验室,化学工程学院,西安710075;
2.西安科技大学化学与化工学院,西安710054

收稿日期:2019-07-02 出版日期:2020-04-28 发布日期:2020-04-28
作者简介:贾园(1988-),女,讲师,博士,主要从事功能性高分子复合材料方面的研究,jiayu_an_happy@126.com。
基金资助:
陕西省教育厅科研计划项目(19JK0741);西安市科技计划创新基金文理专项项目(2019KJWL01);西安文理学院2018年度重点课程项目(KGB201842)

THE PREPARATION OF PSI-CONTAINING BENZOXAZINE AND ITS INFLUENCE ONTHE PROPERTIES OF BISMALEIMIDE ESTER RESIN SYSTEM

JIA Yuan¹, LIU Zhen¹, SHI Rui-feng², YANG Ju-xiang¹

1.The Key Laboratory for Surface Engineering and Remanufacturing in Shaanxi Province,College of Chemical Engineering, Xi'an University, Xi'an 710065, China;
2.School of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China

Received:2019-07-02 Online:2020-04-28 Published:2020-04-28

摘要/Abstract

摘要： 为了改善双马来酰亚胺树脂(BMI)固有的一些缺点,本文以含有氨基的聚硅氧烷(PSi-NH₂)作为胺源,以苯酚作为酚源,通过化学合成的方法制备了结构中含有超支化聚硅氧烷的苯并噁嗪单体(PSi-BOZ),并以其作为改性体系对BMI进行改性,得到了一种新型的PSi-BOZ/BMI共混材料,并研究了PSi-BOZ的添加对BMI固化反应动力学及冲击性能的影响,为新型BMI树脂材料的开发提供了思路。

关键词: 双马来酰亚胺树脂, 苯并噁嗪树脂, 固化动力学, 复合材料

Abstract: In order to improve the poor toughness and heat resistance of bismaleimide (BMI) resin, benzoxazine monomer (BOZ) containing polysiloxane (PSi-BOZ) was synthesized via a chemical method, the hyperbranched polysiloxane with amino terminal groups (PSi-NH₂) and the phenol were chosen as the raw materials. The PSi-BOZ was then used as modification system to add into BMI, and PSi-BOZ/BMI composite with excellent comprehensive performance and good manufacturability was obtained. The influence of the addition of PSi-BOZ on the curing reaction kinetics and impact strength of BMI were also studied. This study is aiming to provide an idea for the development of new BMI resin materials.

Key words: bismaleimide, benzoxazine resin, curing kinetics, composites

中图分类号:

TB332

贾园, 刘振, 师瑞峰, 杨菊香. 含聚硅氧烷结构的苯并噁嗪对双马来酰亚胺树脂改性研究[J]. 复合材料科学与工程, 2020, 0(4): 65-71.

JIA Yuan, LIU Zhen, SHI Rui-feng, YANG Ju-xiang. THE PREPARATION OF PSI-CONTAINING BENZOXAZINE AND ITS INFLUENCE ONTHE PROPERTIES OF BISMALEIMIDE ESTER RESIN SYSTEM[J]. Composites Science and Engineering, 2020, 0(4): 65-71.

参考文献

[1] Shibata M, Satoh K, Ehar S. Thermosetting bismaleimide resins generating covalent and multiple hydrogen bonds[J]. Journal of Applied Polymer Science, 2016, 133(11): 43121.
[2] Han Y, Xie C, Wu Z Z, et al. Preparation and properties of silicon carbide/glass fibres/bismaleimide composites[J]. Journal of Elastomers and Plastics, 2016, 48: 97-104.
[3] Chen Z Y, Yan H X, Liu T Y, et al. Nanosheets of MoS₂ and reduced graphene oxide as hybrid fillers improved the mechanical and tribological properties of bismaleimide composites[J]. Composites Science and Technology, 2016, 125: 47-54.
[4] Phelan J C, Sung C S P. Cure characterization in bis(maleimide)/ diallylbisphenol a resin by fluorescence, FT-IR and UV-reflection spectroscopy[J]. Macromolecules, 1997, 30: 6845-6851.
[5] Shaoquan W, Shangli D, Yu G, et al. Thermal ageing effects on mechanical properties and barely visible impact damage behavior of a carbon fiber reinforced bismaleimide composite[J]. Mater Des, 2017, 115: 213-223.
[6] Zhao Y, Liu W, Seah L K, et al. Delamination growth behavior of a woven E-glass/bismaleimide composite in seawater environment[J]. Compos B Eng, 2016, 106: 332-343.
[7] Lowe A, Fox B, Otieno-Alego V. Interfacial ageing of high temperature carbon/bismaleimide composites[J]. Compos A Appl Sci Manuf, 2002, 33: 1289-1292.
[8] Huo S Q, Wang J, Yang S, et al. A phosphorus-containing phenolic derivative and its application in benzoxazine resins: Curing behavior, thermal, and flammability properties[J]. Journal of applied polymer science, 2016, 133: 43403.
[9] Rao B S, Aruna P. A new thermoset system based on cardanol benzoxazine and hydroxyl benzoxazoline with lower cure temperature[J]. Progress in organic coatings, 2012, 74: 427-434.
[10] Akay M, Spratt G, Meenan B. The effects of long-term exposure to high temperatures on the ILSS and impact performance of carbon fibre reinforced bismaleimide[J]. Combust Sci Technol, 2003, 63: 1053-1059.
[11] Tan Z W, Wu X, Zhang M, et al. Performances improvement of traditional polybenzoxazines by copolymerizing with cyclotriphosphazene-based benzoxazine monomers[J]. Polymer Bulletin, 2015, 72: 1417-1431.
[12] Wang Y X, Ishida H. Cationic ring-opening polymerization of benzoxazines[J]. Polymer, 1999, 40: 4563-4570.
[13] Cao G P, Chen W J, Liu X B. Synthesis and thermal properties of the thermosetting resin based on cyano functionalized benzoxazine[J]. Polymer Degradation and Stability, 2008, 93: 739-744.
[14] Niu S, Yan H, Chen Z, et al. Unanticipated bright blue fluorescence produced from novel hyperbranched polysiloxanes carrying unconjugated carbon-carbon double bonds and hydroxyl groups[J]. Polymer Chemistry, 2016(7): 3747-3755.
[15] Niu S, Yan H, Li S, et al. A multifunctional silicon-containing hyperbranched epoxy: controlled synthesis, toughening bismaleimide and fluorescent properties[J]. Journal of Materials Chemistry C, 2016(4): 6881-6893.