可瓷化PDMS改性聚氨酯泡沫复合材料的制备及其性能研究

复合材料科学与工程 ›› 2020, Vol. 0 ›› Issue (4): 96-100.

可瓷化PDMS改性聚氨酯泡沫复合材料的制备及其性能研究

欧芸¹, 石敏先^1*, 姚亚琳², 黄志雄¹

1.武汉理工大学材料科学与工程学院,武汉430070;
2.北京玻钢院复合材料有限公司,北京102101

收稿日期:2019-07-24 出版日期:2020-04-28 发布日期:2020-04-28
通讯作者: 石敏先(1977-),女,博士,硕士生导师,研究方向为聚合物基复合材料,minxianshi@whut.edu.cn。
作者简介:欧芸(1995-),女,硕士研究生,研究方向为聚合物基复合材料。本文作者还有邹镇岳¹,唐青秀¹。
基金资助:
北京玻钢院复合材料有限公司青年科技创新基金项目(20161h0328)

PREPARATION AND PROPERTIES OF CERAMICIZABLE PDMSMODIFIED POLYURETHANE FOAM COMPOSITES

OU Yun¹, SHI Min-xian^1*, YAO Ya-lin², HUANG Zhi-xiong¹

1.School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China;
2.Beijing FRP Institute Composite Materials Limited Company, Beijing 102101, China

Received:2019-07-24 Online:2020-04-28 Published:2020-04-28

摘要/Abstract

摘要： 硬质聚氨酯泡沫塑料具有低密度、低导热系数和优良的隔热保温性能,但耐热性较差,需提高其耐热性以满足应用要求。本文使用羟基硅油(PDMS)对聚氨酯进行改性,并添加低熔点玻璃粉、滑石粉和高岭土等填料,采用模压成型工艺制备可瓷化PDMS改性聚氨酯泡沫复合材料,研究了高岭土对可瓷化PDMS改性聚氨酯泡沫复合材料压缩强度、导热系数和耐热性能等的影响。结果表明:随着高岭土含量的增加,材料的密度增大,导热系数变大,压缩强度提高;SEM结果显示,800 ℃处理后材料表面生成一层陶瓷化连续相结构;XRD分析表明新生成的陶瓷相为α-石英和斜方锰顽辉石。因此,无机填料的添加有效地提高了硬质聚氨酯泡沫塑料的耐热性。

关键词: 改性聚氨酯, 聚氨酯泡沫, PDMS, 可陶瓷化, 复合材料

Abstract: Rigid polyurethane foam has low density, low thermal conductivity and excellent thermal insulation properties, but its heat resistance is poor which needs to be improved to meet the application requirements. In this paper, the ceramicizable RPUF modified polyurethane foam composite was prepared by using hard polyurethane foam (RPUF) as matrix, hydroxyl silicone oil (PDMS) as modified additive, low melting point glass powder, talc powder and kaolin as ceramicable filler. And, the effects of kaolin on the compressive strength, thermal conductivity and ablative properties at high temperature of the ceramicizable PDMS modified polyurethane foam composites were studied. The results show that with the increase of kaolin content, the density of the material increases, the thermal conductivity increases, and the compressive strength increases. The SEM results show that a ceramic continuous phase structure is formed on the surface of the material after ablation at 800 ℃. XRD analysis indicates that the newly formed ceramic phase was α-quartz and orthorhombic manganese. Therefore, the addition of the inorganic filler effectively improves the heat resistance of the rigid polyurethane foam.

Key words: modified polyurethane, polyurethane foam, PDMS, ceramicizable, composite

中图分类号:

TB332

欧芸, 石敏先, 姚亚琳, 黄志雄. 可瓷化PDMS改性聚氨酯泡沫复合材料的制备及其性能研究[J]. 复合材料科学与工程, 2020, 0(4): 96-100.

OU Yun, SHI Min-xian, YAO Ya-lin, HUANG Zhi-xiong. PREPARATION AND PROPERTIES OF CERAMICIZABLE PDMSMODIFIED POLYURETHANE FOAM COMPOSITES[J]. Composites Science and Engineering, 2020, 0(4): 96-100.

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