碳化蚕丝织物/PDMS/Fe3O4复合柔性应变/磁双模式传感器的制备与性能研究

doi:10.19936/j.cnki.2096-8000.20221028.009

复合材料科学与工程 ›› 2022, Vol. 0 ›› Issue (10): 56-62.DOI: 10.19936/j.cnki.2096-8000.20221028.009

碳化蚕丝织物/PDMS/Fe₃O₄复合柔性应变/磁双模式传感器的制备与性能研究

贡永青^1,2, 刘玉慧^1,2, 闫蕾^1,2, 赵雪^1,2, 吴琪琳^1,2*

1.东华大学纤维材料改性国家重点实验室,上海201620;
2.东华大学材料科学与工程学院,上海201620

收稿日期:2021-11-02 出版日期:2022-10-28 发布日期:2022-11-01
通讯作者: 吴琪琳(1970-),女,博士,研究员,主要从事碳材料方面的研究,wql@dhu.edu.cn。
作者简介:贡永青(1997-),男,硕士研究生,主要从事碳基柔性传感器方面的研究。
基金资助:
国家自然科学基金重大项目(52090033/52090030)

Preparation and performance study of carbonized silk/PDMS/Fe₃O₄ composite flexible strain/magnetic dual-mode sensors

GONG Yong-qing^1,2, LIU Yu-hui^1,2, YAN Lei^1,2, ZHAO Xue^1,2, WU Qi-lin^1,2*

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China;
2. College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

Received:2021-11-02 Online:2022-10-28 Published:2022-11-01

摘要/Abstract

摘要： 本文以双绉丝绸为原料,通过高温热处理得到具有导电性的碳化蚕丝布,并与聚二甲基硅氧烷(PDMS)弹性体和Fe₃O₄纳米颗粒复合,制备了一种柔性应变/磁双模式传感器。该传感器应变范围为0%~60%,表现出可拉伸性,其应变灵敏度(GF)最高为9.49,并且在200多次拉伸/回复过程中具有良好的稳定性。Fe₃O₄的添加赋予了传感器对50 mT以下小磁场的响应,当Fe₃O₄的添加量为25wt%时,其磁场灵敏度(GF_m)可达39.73%/T。该传感器能够准确地监测手指弯曲和磁场大小,实现了双模式传感。最终成功制备了一种非接触式的磁电开关,实现了可视化的磁场检测。

关键词: 蚕丝, 碳化织物, 应变传感, 磁性传感, 双模式传感器, 复合材料

Abstract: The high electrical conductivity carbonized silk fabrics were prepared by using crepe de chine silk as raw materials under high temperature heat treatment, and were combined with polydimethylsiloxane (PDMS) elastomer and Fe₃O₄ nanoparticles to prepare a flexible magnetic/strain dual-mode sensor. The sensors exhibited stretchability in a strain range of 0%~60%, with a maximum strain sensitivity (GF) of 9.49, and good stability over 200 stretching/recovery process. The addition of Fe₃O₄endowed the sensor with a response to a small magnetic field below 50 mT. When the addition of Fe₃O₄was 25wt%, its magnetic field sensitivity (GF_m) could reach to 39.73%/T. The sensor could accurately monitor finger bending and magnetic field, realizing dual-mode sensing. Finally, a non-contact magneto-electrical switch was successfully prepared, making the visual magnetic field detection possible.

Key words: silk, carbonized fabric, strain sensing, magnetic sensing, dual-mode sensor, composites

中图分类号:

TB332

贡永青, 刘玉慧, 闫蕾, 赵雪, 吴琪琳. 碳化蚕丝织物/PDMS/Fe₃O₄复合柔性应变/磁双模式传感器的制备与性能研究[J]. 复合材料科学与工程, 2022, 0(10): 56-62.

GONG Yong-qing, LIU Yu-hui, YAN Lei, ZHAO Xue, WU Qi-lin. Preparation and performance study of carbonized silk/PDMS/Fe₃O₄ composite flexible strain/magnetic dual-mode sensors[J]. COMPOSITES SCIENCE AND ENGINEERING, 2022, 0(10): 56-62.

参考文献

[1] HUA Q, SUN J, LIU H, et al. Skin-inspired highly stretchable and conformable matrix networks for multifunctional sensing[J]. Nature Communications, 2018, 9(1): 244.
[2] CHEN G, LI Y, BICK M, et al. Smart textiles for electricity generation[J]. Chemical Reviews, 2020, 120(8): 3668-3720.
[3] 孟靖达, 冯岑. 智能可穿戴技术的发展与应用[J]. 现代丝绸科学与技术, 2021, 36(2): 37-42.
[4] 许培俊, 程静琪, 张宁, 等. 彩色玻璃纤维的制备及其变色响应性[J]. 复合材料科学与工程, 2020(2): 44-47.
[5] 王翔, 王钧, 钟龄. 碳纤维复合材料的电阻-应变传感特性研究[J]. 玻璃钢/复合材料, 2004(4): 33-35.
[6] ZHOU Q, JI B, HU B, et al. Tilted magnetic micropillars enabled dual-mode sensor for tactile/touchless perceptions[J]. Nano Energy, 2020, 78: 105382.
[7] SOURI H, BABERJEE H, JUSUFI A, et al. Wearable and stretchable strain sensors: Materials, sensing mechanisms, and applications[J]. Advanced Intelligent Systems, 2020, 2(8): 2000039.
[8] LU L, JIANG C, HU G, et al. Flexible noncontact sensing for human-machine interaction[J]. Advanced Materials, 2021, 33(16): 2100218.
[9] 张琪, 王太宏, 段小川. 基于压电薄膜的非接触式人体生理信号监测椅[J]. 压电与声光, 2020, 42(4): 515-518.
[10] GAO H L, WANG ZY, CUI C, et al. A highly compressible and stretchable carbon spring for smart vibration and magnetism sensors[J]. Advanced Materials, 2021, 33(39): 2102724.
[11] LI F, LIUY, SHI X, et al. Printable and stretchable temperature-strain dual-sensing nanocomposite with high sensitivity and perfect stimulus discriminability[J]. Nano Letters, 2020, 20(8): 6176-6184.
[12] ZHOU K, XU W, YU Y, et al. Tunable and nacre-mimetic multifunctional electronic skins for highly stretchable contact-noncontact sensing[J]. Small, 2021, 17(31): 2100542.
[13] OLIVEROS-MATA E S, CANON-BERMUDEZ G S, HA M, et al. Printable anisotropic magnetoresistance sensors for highly compliant electronics[J]. Applied Physics A, 2021, 127(4): 280.
[14] 门阔, 赵鸿滨, 魏峰, 等. 磁性传感材料与器件研究进展[J]. 材料导报, 2021, 35(15): 15056-15064.
[15] FANG F, LI YQ, HUANG GW, et al. Electrical anisotropy and multidimensional pressure sensor of aligned Fe₃O₄@silver nanowire/polyaniline composite films under an extremely low magnetic field[J]. RSC Advances, 2017, 7(8): 4260-4268.
[16] MAKUSHKO P, OLIVEROS-MATA E S, CANON-BERMUDEZ G S, et al. Flexible magnetoreceptor with tunable intrinsic logic for on-skin touchless human-machine interfaces[J]. Advanced Functional Materials, 2021, 31(25): 2101089.
[17] CANON-BERMUDEZ G S, MAKAROVD. Magnetosensitive e-skins for interactive devices[J]. Advanced Functional Materials, 2021, 31(39): 2007788.
[18] 杨坤, 秦岩, 高冰, 等. 磁性橡胶阻尼复合材料的研究[J]. 玻璃钢/复合材料, 2012(S1): 56-58.
[19] LIU S, WANG S, XUAN S H, et al. Highly flexible multilayered e-skins for thermal-magnetic-mechanical triple sensors and intelligent grippers[J]. ACS Applied Materials & Interfaces, 2020, 12(13): 15675-15685.
[20] SU L, JIN D D, PAN C F, et al. A mobile magnetic pad with fast light-switchable adhesion capabilities[J]. Bioinspiration & Biomimetics, 2021, 16(5): 055005.
[21] MAO G, DRACK M, KARAMI-MOSAMMAM M, et al. Soft electromagnetic actuators[J]. Science Advances, 2020, 6(26): eabc0251.
[22] MELZER M, KALTENBRUNNER M, MAKAROV D, et al. Imperceptible magnetoelectronics[J]. Nature Communications, 2015, 6(1): 6080.
[23] DING L, XUAN S H, FENG J B, et al. Magnetic/conductive composite fibre: A multifunctional strain sensor with magnetically driven property[J]. Composites Part A: Applied Science and Manufacturing, 2017, 100: 97-105.
[24] DING L, WANG Y, SUN C, et al. Three-dimensional structured dual-mode flexible sensors for highly sensitive tactile perception and noncontact sensing[J]. ACS Applied Materials & Interfaces, 2020, 12(18): 20955-20964.
[25] LIU Y F, FU Y F, LI Y Q, et al. Bio-inspired highly flexible dual-mode electronic cilia[J]. Journal of Materials Chemistry B, 2018, 6(6): 896-902.
[26] HUANG P, LI Y Q, YU X G, et al. Bioinspired flexible and highly responsive dual-mode strain/magnetism composite sensor[J]. ACS Applied Materials & Interfaces, 2018, 10(13): 11197-11203.
[27] WANG C Y, LI X, GAO E L, et al. Carbonized silk fabric for ultrastretchable, highly sensitive, and wearable strain sensors[J]. Advanced Materials, 2016, 28(31): 6640-6648.
[28] WANG C Y, XIA K L, ZHANG Y Y, et al. Silk-based advanced materials for soft electronics[J]. Accounts of Chemical Research, 2019, 52(10): 2916-2927.
[29] LIU J, SUN Z, DENG Y, et al. Highly water-dispersible biocompatible magnetite particles with low cytotoxicity stabilized by citrate groups[J]. Angewandte Chemie International Edition, 2009, 48(32): 5875-5879.

碳化蚕丝织物/PDMS/Fe₃O₄复合柔性应变/磁双模式传感器的制备与性能研究

Preparation and performance study of carbonized silk/PDMS/Fe₃O₄ composite flexible strain/magnetic dual-mode sensors

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