石英纤维增强环氧树脂基复合材料的激光烧蚀行为

doi:10.19936/j.cnki.2096-8000.20241028.002

复合材料科学与工程 ›› 2024, Vol. 0 ›› Issue (10): 11-16.DOI: 10.19936/j.cnki.2096-8000.20241028.002

石英纤维增强环氧树脂基复合材料的激光烧蚀行为

陈松^1,2,3, 甄岳泽^1,2,3, 马壮^1,2,3, 高丽红^1,2,3*, 王东红^4,5

1.北京理工大学材料学院, 北京 100081;
2.冲击环境材料技术国家级重点实验室, 北京 100081;
3.北京理工大学唐山研究院, 唐山 063000;
4.中国电子科技集团公司第三十三研究所, 太原 030006;
5.山西省电磁防护材料与技术重点实验室, 太原 030006

收稿日期:2023-08-24 出版日期:2024-10-28 发布日期:2024-12-10
通讯作者: 高丽红(1984—),女,博士,教授,博士生导师,研究方向为高温高能特种防护材料,gaolihong@bit.edu.cn。
作者简介:陈松(1997—),女,硕士,研究方向为高温高能特种防护材料。
基金资助:
国家自然科学基金(52073029);山西省科技创新团队专项基金(202204051001001)

Laser ablation behavior of quartz fiber reinforced epoxy resin matrix composites

CHEN Song^1,2,3, ZHEN Yueze^1,2,3, MA Zhuang^1,2,3, GAO Lihong^1,2,3*, WANG Donghong^4,5

1. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China;
2. National Key Laboratory of Science and Technology on Materials under Shock and Impact, Beijing 100081, China;
3. Tangshan Research Institute, Beijing Institute of Technology, Tangshan 063000, China;
4. No.33 Research Institute of China Electronics Technology Group Corporation, Taiyuan 030006, China;
5. Electromagnetic Protection Materials and Technology Key Laboratory of Shanxi Province, Taiyuan 030006, China

Received:2023-08-24 Online:2024-10-28 Published:2024-12-10

摘要/Abstract

摘要： 以环氧树脂为基体,以石英纤维为增强体,制备了石英纤维增强环氧树脂基复合材料,探究了不同功率密度的高能连续激光对石英纤维增强环氧树脂基复合材料的辐照效应,分析了功率密度分别为100 W/cm²、500 W/cm²和1 000 W/cm²的激光对辐照样品宏微观形貌和质量烧蚀率的影响,并通过温度演变数据和树脂热解阈值模型对烧蚀行为作进一步分析。研究结果表明:激光作用于复合材料表面后,沉积的能量将造成环氧树脂基体的热解,随着激光功率密度增加,环氧树脂基体热解程度增加,复合材料表面烧蚀区域不断扩大,质量烧蚀率增加,对复合材料的破坏加剧。环氧树脂基体热解生成的气体和残炭起到了消耗能量、遮蔽激光、阻隔热量等作用,使复合材料具备了一定的抗激光烧蚀性能。

关键词: 激光辐照, 复合材料, 环氧树脂基体热解, 残炭, 烧蚀行为

Abstract: Quartz fiber reinforced epoxy resin matrix composites were prepared using epoxy resin as the matrix and quartz fiber as the reinforcement. The study investigated the irradiation effect of high-energy continuous laser with different power densities on quartz fiber reinforced epoxy resin matrix composites. The study analyzed the effects of laser with power densities of 100 W/cm², 500 W/cm², and 1 000 W/cm² on the macroscopic and microscopic morphology and the mass ablation rate of irradiated samples. Through the temperature evolution data and resin pyrolysis threshold model, the ablation behavior was further analyzed. Results indicates that after laser irradiation on the surface of composites, the deposited energy causes epoxy resin matrix pyrolysis. As the laser power density increases, the degree of epoxy resin matrix pyrolysis increases, the ablation region on the surface of the composites continues to expand, and the mass ablation rate increases, the damage to the composites intensifies. The generation of gas and residual carbon through epoxy resin matrix pyrolysis play a role in energy consumption, shielding lasers and blocking heat. The composites have a certain resistance to laser ablation.

Key words: laser irradiation, composites, epoxy resin matrix pyrolysis, residual carbon, ablation behavior

中图分类号:

TB332

陈松, 甄岳泽, 马壮, 高丽红, 王东红. 石英纤维增强环氧树脂基复合材料的激光烧蚀行为[J]. 复合材料科学与工程, 2024, 0(10): 11-16.

CHEN Song, ZHEN Yueze, MA Zhuang, GAO Lihong, WANG Donghong. Laser ablation behavior of quartz fiber reinforced epoxy resin matrix composites[J]. COMPOSITES SCIENCE AND ENGINEERING, 2024, 0(10): 11-16.

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石英纤维增强环氧树脂基复合材料的激光烧蚀行为

Laser ablation behavior of quartz fiber reinforced epoxy resin matrix composites

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