复合材料科学与工程 ›› 2024, Vol. 0 ›› Issue (9): 48-51.DOI: 10.19936/j.cnki.2096-8000.20240928.007

• 基础研究 • 上一篇    下一篇

残留单体丙烯腈对PAN基碳纤维制备的影响研究

黄大明, 唐立鑫, 孙军涛, 王炜   

  1. 威海拓展纤维有限公司,威海 264200
  • 收稿日期:2024-03-25 出版日期:2024-09-28 发布日期:2024-10-18
  • 作者简介:黄大明(1982—),男,硕士研究生,高级工程师,研究方向为碳纤维的制备、研发及检测,842985951@qq.com。

Research on the effect of residual monomer acrylonitrile on the preparation of PAN-based carbon fiber

HUANG Daming, TANG Lixin, SUN Juntao, WANG Wei   

  1. Weihai Tuozhan Fiber Co., Ltd., Weihai 264200, China
  • Received:2024-03-25 Online:2024-09-28 Published:2024-10-18

摘要: 本文通过气相色谱法检测PAN纺丝液中残留单体含量,研究了残留单体量对生产环境的影响,并分析得出残留单体量的最小标准。研究了残留单体对纺丝液性质的影响,发现由于持续聚合反应,残留单体丙烯腈会由于自身的反应提高纺丝液的黏度和固含量;进一步研究了残留单体对碳纤维强度和起毛量的影响,发现残留单体的减少有利于碳纤维生产以及碳纤维性能提升,并通过分析得出适应碳纤维生产的残留单体量。另外,从脱单过程的真空度、温度、薄膜表面积等方面出发,分析降低残留单体量的相关方法的影响,有助于合理化生产的进行。

关键词: 碳纤维, 聚合, 残留单体, 复合材料

Abstract: This article detects the content of residual monomer in the PAN spinning solution through gas chromatography, studies the impact of the residual monomer content on the production environment, and analyzes to obtain the minimum standard of the residual monomer content. It studies the effect of the residual monomer on the properties of the spinning solution, and finds that due to the continuous polymerization reaction, the residual monomer acrylonitrile will increase the viscosity and solid content of the spinning solution due to its own reaction. It further studies the impact on the strength and fuzziness of the carbon fiber, and finds that with the reduction of the residual monomer, it will be beneficial to the production of the carbon fiber and the improvement of the performance of the carbon fiber, and analyzes to obtain the requirements for the residual monomer content suitable for the production of carbon fiber. In addition, starting from aspects such as the vacuum degree, temperature, and film surface area in the de-monomerization process, it analyzes the impact of related methods to reduce the residual monomer content, and helps the rationalization of production.

Key words: carbon fiber, polymerization, residual monomers, composites

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