复合材料科学与工程 ›› 2020, Vol. 0 ›› Issue (6): 121-128.

• 综述 • 上一篇    

树脂基复合材料与金属材料胶接体系研究进展

付文强, 王小兵*, 王宝春, 徐洪敏   

  1. 中国兵器工业集团第五三研究所,济南250031
  • 收稿日期:2019-09-10 出版日期:2020-06-28 发布日期:2020-06-28
  • 通讯作者: 王小兵(1978-),男,博士,研究员,主要从事功能复合材料方面的研究,wangxb1978@hotmail.com。
  • 作者简介:付文强(1996-),男,硕士研究生,主要从事轻质结构装甲方面的研究。

RESEARCH PROGRESS ON ADHESION SYSTEM OF RESIN-BASED COMPOSITES AND METAL MATERIALS

FU Wen-qiang, WANG Xiao-bing*, WANG Bao-chun, XU Hong-min   

  1. China North Industries Group Corporation Institute 53, Jinan 250031, China
  • Received:2019-09-10 Online:2020-06-28 Published:2020-06-28

摘要: 树脂基复合材料由于具有优异的性能而一直广受关注,其在应用过程中不可避免地存在与金属等异种材料的连接问题。本文以树脂基复合材料在实际生产应用中的发展历程为出发点,从化学键连接理论、机械互锁连接理论、表面润湿和吸附理论、双电层连接理论等方面简要阐述了复合材料和金属材料胶接体系设计的相关理论,并从物理和化学两方面介绍了几种常用的表面预处理方法,其中包括喷砂、磨蚀、溶剂清洗等物理预处理方法与化学蚀刻、阳极氧化、等离子体处理、硅烷偶联剂处理及激光处理等化学预处理方法,最后列举了有关胶粘剂改性的一些思路。

关键词: 表面处理, 复合材料, 胶接, 金属材料, 胶粘剂

Abstract: Resin-based composite materials have been receiving much attention due to their excellent mechanical properties and good designability, and they have also been widely used in aerospace and military fields. As composite materials are further deployed in various fields, defects in them begin to emerge. Unlike conventional metal materials, composite materials cannot be perforated to use bolted joints without compromising their overall performance. The manufacture of composite materials has great uncertainty, and the stability of their performance is difficult to control. Therefore, in practical applications, many parts still need to use traditional metal materials. This brings up a new problem, that is, the connection of composite materials to metal materials. As stated above, if the composite material is bolted, the perforating operation prior to joining will cut the reinforcing fibers resulting in a decrease in the overall performance of the composite. This operation will also cause stress concentration at the opening, further reducing its performance and long-term stability, and there is also the possibility of electrochemical corrosion between the composite material and the metal material. To this end, researchers around the world have begun to focus on the adhesion between the composite materials and the metal materials, using a variety of adhesives as an intermediate layer to join them together. This paper first introduces the development history of resin-based composite materials in practical applications. Then the related theories of designing adhesion systems of composite materials and metal materials are briefly described, from chemical bond connection theory, mechanical interlocking connection theory, surface wetting and adsorption theory, and electric double layer connection theory. Then several common surface pretreatment methods are introduced, including physical pretreatment methods such as sand blasting and abrasion, solvent cleaning, and chemical pretreatment methods such as chemical etching, anodizing, plasma treatment, silane coupling agent treatment, laser treatment. Finally, some ideas for the modification of adhesives are listed.

Key words: surface treatments, composite, adhesion, metal, adhesive

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