玻璃钢/复合材料 ›› 2009, Vol. 209 ›› Issue (4): 32-34.

• 材料研究 • 上一篇    下一篇

碳纳米管/PMMA/PVAC复合膜气敏性能研究

  

  1. 1北京玻钢院复合材料有限公司,北京102101;2北京化工大学碳纤维及复合材料研究所,北京100029
  • 出版日期:2009-07-28 发布日期:2009-04-25
  • 作者简介:柴红梅(1980),女,工程师,主要从事高性能环氧树脂及其复合材料研究。

ELECTRICAL RESISTANCE RESPONSE OF CARBON NANOTUBE
/ PMMA / PVAC COMPOSITE FILM

  • Online:2009-07-28 Published:2009-04-25

摘要:

本文将一定量的PMMA、PVAc和碳纳米管在四氢呋喃溶剂中混合,通过超声分散和溶液浇铸工艺制备了碳纳米管/PMMA/PVAc复合膜。研究了在0.44.1ppt乙酸乙酯气氛下,碳纳米管/PMMA/PVAc复合膜电阻与气氛浓度的变化关系。研究表明:在0.44.1ppt气氛下,碳纳米管/PMMA/PVAc复合膜电阻随着乙酸乙酯气氛浓度的增大而增大,复合膜对乙酸乙酯气氛具有较优的敏感性,且同时随着复合膜中PMMA含量增加,复合膜电阻增加,即气敏性增加。因此,PMMA/PVAC共混物在气敏材料的应用领域上具有潜在的价值。

关键词: 碳纳米管, PMMA, PVAc, 电阻响应

Abstract:

The solution was prepared by mixing PMMA/PVAc with carbon nanotubes in terahydrofuran (THF).Thin films of carbon nanotube/poly(methyl methacrylate)(PMMA)/poly(vinyl acetate)(PVAc) composite film were produced by solution casting.Electrical resistance responses of carbon nanotube/PMMA/PVAc composite film against various ethyl acetate vapors at low concentrations were investigated.The results indicated that the composites had high sensitivity to different ethyl acetate vapors concentration and the electrical resistance increased with increasing PMMA content.So compatible blends of poly(methyl methacrylate) and poly(vinyl acetate) would be a candidate to be used as a gas sensing material to detect,quantify and discriminate various organic vapors.