醇类分子对环氧树脂体系流变及固化行为的影响

玻璃钢/复合材料 ›› 2018, Vol. 0 ›› Issue (11): 27-30.

醇类分子对环氧树脂体系流变及固化行为的影响

李肇晨, 张文卿, 杨小平, 隋刚^*

北京化工大学材料科学与工程学院,北京100029

收稿日期:2018-09-29 出版日期:2018-11-28 发布日期:2018-11-28
通讯作者: 隋刚(1972-),男,博士,教授,硕士生/博士生导师,主要从事复合材料方面的研究,suigang@mail.buct.edu.cn。
作者简介:李肇晨(1994-),男,硕士研究生,主要从事复合材料方面的研究。
基金资助:
国家自然科学基金面上项目(U1664251);中国汽车产业创新发展联合基金

EFFECT OF ALCOHOLS ON THE RHEOLOGICAL AND CURING BEHAVIOR OF EPOXY RESIN SYSTEM

LI Zhao-chen, ZHANG Wen-qing, YANG Xiao-ping, SUI Gang^*

School of Materials Science and Engineering, Beijing University of Chemical and Technology, Beijing 100029, China

Received:2018-09-29 Online:2018-11-28 Published:2018-11-28

摘要/Abstract

摘要： 为了研究醇类小分子对环氧/胺体系流变和固化行为的影响,对环氧/胺体系、环氧/胺/小分子醇体系及环氧/胺/咪唑/小分子醇体系进行了DSC、流变及力学性能测试,比较了三个体系的综合性能。实验发现以小分子醇C₄H₁₀O₂作为功能性组分加入环氧树脂体系中有明显的促进效果,且在咪唑类促进剂2-乙基-4-甲基咪唑存在的情况下,C₄H₁₀O₂的促进效果更明显,两种体系均具有良好的力学性能。

关键词: 环氧树脂, 醇, 快速固化, 固化动力学, 流变学

Abstract: In order to study the effect of micromolecule alcohol on the epoxy/amine system, DSC, rheological and mechanics testing of the epoxy/amine system, epoxy/amine/micromolecule alcohol system, and epoxy/amine/imidazole/small molecule alcohol system were studied in this experiment. The overall performance of the three systems was compared. It is found that the addition of the micromolecular alcohol C₄H₁₀O₂ as an functional additive into the epoxy resin system has a significant promoting effect. In the presence of the imidazole accelerator 2-ethyl-4-methyl imidazole, the promotion effect of C₄H₁₀O₂ is better, and both two systems have good mechanical properties.

Key words: epoxy resin, alcohol, rapid curing, curing kinetics, rheological

中图分类号:

TB332

李肇晨, 张文卿, 杨小平, 隋刚. 醇类分子对环氧树脂体系流变及固化行为的影响[J]. 玻璃钢/复合材料, 2018, 0(11): 27-30.

LI Zhao-chen, ZHANG Wen-qing, YANG Xiao-ping, SUI Gang. EFFECT OF ALCOHOLS ON THE RHEOLOGICAL AND CURING BEHAVIOR OF EPOXY RESIN SYSTEM[J]. Fiber Reinforced Plastics/Composites, 2018, 0(11): 27-30.

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