定型压力对PES薄膜改性复合材料拉伸性能的影响研究

玻璃钢/复合材料 ›› 2018, Vol. 0 ›› Issue (12): 57-61.

定型压力对PES薄膜改性复合材料拉伸性能的影响研究

瞿立, 李进^*, 康少付, 张佃平

宁夏大学宁夏光伏材料重点实验室,银川750021

收稿日期:2018-04-23 出版日期:2018-12-28 发布日期:2018-12-28
通讯作者: 李进(1964-),女,博士,教授,主要从事复合材料的结构设计、制造、仿真以及光伏材料方面的研究,li-jin@163.com。
作者简介:瞿立(1994-),男,硕士,主要从事复合材料的制备工艺、性能测试及模拟仿真方面的研究。
基金资助:
宁夏自然科学基金(NZ17259);福建省特种先进材料重点实验室资助课题

EFFECT OF THE TACKIFIED PRESSURE ON THE TENSILE PROPERTY OF THE PES FILM MODIFIED COMPOSITES

QU Li, LI Jin, KANG Shao-fu, ZHANG Dian-ping

Key Laboratory of Ningxia for Photovoltaic Materials, Ningxia University, Yinchuan 750021, China

Received:2018-04-23 Online:2018-12-28 Published:2018-12-28

摘要/Abstract

摘要： 复合材料以优异的综合性能被广泛用于航空航天和汽车等领域,但高昂的制造成本阻碍了其进一步应用;低成本制造高性能复合材料一直是研究热点。针对真空辅助成型(VARTM)工艺所得复合材料力学性能差的不足,将聚醚砜(PES)薄膜置于预制体纤维层间,在一定温度和定型压力下制得改性预制体,最后采用VARTM工艺制得改性复合材料。研究了0.1 MPa、0.3 MPa和0.6 MPa定型压力下所得改性复合材料的拉伸性能,结果表明,与未改性复合材料相比,改性复合材料试样的拉伸强度和模量性能均得到提高。三种定型压力下改性复合材料的拉伸强度分别提高了16.78%、41.21%和29.47%,拉伸模量分别提高了2.48%、19.01%和13.22%,为低成本制造高性能复合材料提供了参考。

关键词: 复合材料, 定型压力, 聚醚砜薄膜, VARTM工艺, 拉伸性能

Abstract: The composites have widely used in the aerospace and automotive field for the excellent performance. However, the high cost has hindered its further use and production of the high property composites with low cost has obtained the most concerns. In the present study, the hot-press tackified process was provided to improve the disadvantage of the VARTM of low mechanical property by using the PES (Polyethersulfone) film material interval stacked into the fabrics under certain temperature and pressure to get the modified preforms. Finally, the modified composites were obtained with the VARTM on the modified preforms. The pressures of 0.1 MPa, 0.3 MPa and 0.6 MPa were used to study the effect of tackifier pressure on the tensile strength and modulus on the modified composites, as compared to the unmodified composites. The results indicate that the tensile strength of the modified composites for the three tackifier pressures have improved by 16.78%, 41.21% and 29.47% respectively, and the tensile modulus have improved by 2.48%, 19.01% and 13.22%, which provide the guidance to obtain the high performance composites with low cost process of VARTM.

Key words: composites, tackified pressure, PES film, VARTM, tensile property

中图分类号:

TB332

瞿立, 李进, 康少付, 张佃平. 定型压力对PES薄膜改性复合材料拉伸性能的影响研究[J]. 玻璃钢/复合材料, 2018, 0(12): 57-61.

QU Li, LI Jin, KANG Shao-fu, ZHANG Dian-ping. EFFECT OF THE TACKIFIED PRESSURE ON THE TENSILE PROPERTY OF THE PES FILM MODIFIED COMPOSITES[J]. Fiber Reinforced Plastics/Composites, 2018, 0(12): 57-61.

参考文献

[1]Robertson C F. Resin transfer molding of aerospace resins-a review[J]. British Polymer Journal, 2010, 20(5): 417-429.
[2]Kang M K, Lee W I, Kelly P A. Analysis of vacuum bag resin trans-fer molding process[J]. Composites Part A, 2001, 32(11): 1553-1560.
[3]Brouwer W D, Van Herpt E C F C, Labordus M. Vacuum injection molding for large structural applications[J]. Composites Part A, 2003, 34(6): 551-558.
[4]Li W, Krehl J, Gillespie J W, et al. Process and performance evaluation of the vacuum-assisted process[J]. Journal of Composites Materials, 2004, 38(20): 1803-1814.
[5]Duan Y, Tan Z, Zhao Y, et al. Compression responses of preform in vacuum infusion process[J]. China Journal Aeronautics, 2008, 21(4): 370-377.
[6]Mishra S C. Low cost polymer composites with rural resources[J]. Journal of Reinforced Plastics & Composites, 2009, 28(28): 2183-2188.
[7]Prabhu R, Frazer, Akshay, et al. Development and characterization of low cost bamboo fiber reinforced polymer composites[J]. American Journal of Materials Science, 2017, 7(5): 130-134.
[8]李柏松, 王继辉, 邓京兰. 真空辅助RTM成型技术的研究[J]. 玻璃钢/复合材料, 2001(1): 17-19.
[9]Singh A K, Mehra D S, Niyogi U K. Effect of tackifier and crosslinkers on electron beam curable polyurethane pressure sensitive adhesive[J]. Radiation Physics and Chemistry, 2012, 81(5): 547-552.
[10]Hillermeier R W, Seferis J C. Interlayer toughening of resin transfer molding composites[J]. Composites Part A, 2001, 32(5): 721-729.
[11]Hillermeier R W, Hayes B S, Seferis J C. Processing of highly elas-tomeric toughened cyanate esters through a modified resin transfer molding technique[J]. Polymer Composites, 1999, 20(1): 155-158.
[12]Hillermeier R W, Hayes B S. Tckifier/binder toughened resin transfer molding composites[J]. Journal of advanced materials-Covina, 2000, 31(4): 52-59.
[13]乌云其其格, 胡仁伟, 何丹, 等. 定型剂对复合材料性能影响的研究[J]. 高科技纤维与应用, 2013, 38(2): 31-35.
[14]廖永波, 梁子青, 李玲. 定型剂对复合材料力学性能的影响[J]. 化工新型材料, 2006, 34(10): 62-65.
[15]高龙飞, 陈萍, 陈吉平, 等. 复合材料预成型体粉末定型剂的制备[J]. 玻璃钢/复合材料, 2016(1): 67-70.
[16]Pelia R, Seferis J C, Karaki T, et al. Effects of nanoclay on the thermal and rheological properties of a VARTM epoxy resin[J]. Journal of Thermal Analysis & Calorimetry, 2009, 96(2): 587-592.